2,3-Difluorophenylboronic acid 2,3-二氟苯硼酸

CAS 121219-16-7 MFCD01863170

化学结构图

121219-16-7
SMILES: OB(O)C1C=CC=C(F)C=1F

化学属性

Mol. FormulaC6H5BF2O2
Mol. Weight158
Melting Point225
TSCANo
Density1.35

别名和识别编码

Chemical Name2,3-Difluorophenylboronic acid
CAS Number121219-16-7
Alfabeta NameDIFLUOROPHENYLBORONICACID 23-,
MDL NumberMFCD01863170
Synonym 2,3-Difluorobenzeneboronic Acid (contains varying amounts of Anhydride) 2,3-Difluorobenzeneboronic acid 2,3-二氟苯硼酸
PubChem Substance ID87559498
Reaxys-RN6594341
EC Number000-000-0
Beilstein Registry Number6594341
Chemical Name Translation2,3-二氟苯硼酸
LabNetwork Molecule IDLN00117880
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分类

  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents
  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • 1. Noel, T.; et al., Suzuki-Miyaura Cross-Coupling Reactions in Flow: Multistep Synthesis Enabled by a Microfluidic Extraction Angew. Chem. Int. Ed. Engl. 50 , 5943-5946, (2011)
  • 2. Brown, D. G.; et al., 2,6-Disubstituted pyrazines and related analogs as NR2B site antagonists of the NMDA receptor with anti-depressant activity Bioorg. Med. Chem. Lett. 21 , 3399-3403, (2011)
  • 3. Kloser, E.; et al., Synthesis of 5-(Fluorophenyl)tocopherols as Novel Dioxin Receptor Antagonists J. Org. Chem. , 2450-2457, (2011)

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  6. Disubstituted Aryl Boronic Acids - Aryl Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Alkyl
  1. Functional Group 官能团索引
  2. boronic acid