(R,R)-Tsdpen (1R,2R)-(-)-N-(对甲基苯磺酰基)-1,2-二苯基乙二胺

CAS 144222-34-4 MFCD02093428

化学结构图

144222-34-4
SMILES: CC1C=CC(=CC=1)S(=O)(=O)N[C@@H]([C@H](N)C1C=CC=CC=1)C1C=CC=CC=1 |&1:11,12|

化学属性

Mol. FormulaCH3C6H4SO2NHCH(C6H5)CH(C6H5)NH2
Mol. Weight366.48
Melting Point126-130
TSCANo
Density1.224
Refractive index-30 ° (C=0.4, CHCl3)
Appearance white xtl.

别名和识别编码

Chemical Name(R,R)-Tsdpen
CAS Number144222-34-4
Alfabeta NameAMINODIPHENYLETHYLTOLUENESULFONAMIDE RRNP212(())-------,,
MDL NumberMFCD02093428
Synonym (1R,2R)-(-)-N-对甲苯磺酰基-1,2-二苯基乙二胺 (R,R)-N-(对甲苯磺酰基)-1,2-二苯基乙二胺 ########
PubChem Substance ID24871941
Reaxys-RN8637103
EC Number250-023-7
Beilstein Registry Number2384789
Chemical Name Translation(1R,2R)-(-)-N-(对甲基苯磺酰基)-1,2-二苯基乙二胺
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, Organic Building Blocks, Polyamines, Protected Amines
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, Organic Building Blocks, Polyamines, Protected Amines

产品应用

  • (R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide is used as a catalyst in stereoselective preparation of aromatic ketone derivatives as well as other chiral organic compounds.

相关文献及参考

  • Tanis, S.P. et al.: Tetrahed. Assym., 17, 2154 (2006); Morris, D.J. et al.: Tetrahed. Lett., 51, 209 (2010);

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

其他信息

  • TCI Shanghai:(R,R)-N-(2-氨基-1,2-二苯乙基)-对甲苯磺酰胺 (R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide,>;98.0%(T)(144222-34-4)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Epoxidation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Hydrogenation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Amides - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Polyamines - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphonic/Phosphinic Acids 膦酸
  1. CATHy Catalyst
  2. Nitrogen
  1. DPEN
  2. Nitrogen
  1. Ligands
  2. Nitrogen
  1. CATHy Catalyst
  2. 96-7650 CATHy™ Catalyst Kit for Asymmetric Transfer Hydrogenation of Ketones and Imines
  1. Catalysts
  2. 96-7650 CATHy™ Catalyst Kit for Asymmetric Transfer Hydrogenation of Ketones and Imines

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