(R,R)-(-)-N,N’-Bis(3,5-di-Tert-Butylsalicylidene)-1,2-Cyclohexanediaminomanganese(Iii) Chloride 雅可布逊晶体

CAS 138124-32-0 MFCD02101664

化学结构图

138124-32-0
SMILES: CC(C)(C)C1=CC2C=N[C@@H]3CCCC[C@H]3N=CC3=CC(=CC(=C3O[Mn](Cl)OC=2C(=C1)C(C)(C)C)C(C)(C)C)C(C)(C)C |c:20,31,t:4,7,16|

化学属性

Mol. FormulaC36H52ClMnN2O2
Mol. Weight635.21
Melting Point330-332 °C (lit.)
Appearance brown pwdr.

别名和识别编码

Chemical Name(R,R)-(-)-N,N’-Bis(3,5-di-Tert-Butylsalicylidene)-1,2-Cyclohexanediaminomanganese(Iii) Chloride
Synonym Jacobsen 催化剂 (R,R)-Jacobsen’s catalyst (R,R)-Jacobsen 催化剂 (R,R)-Jacobsen 催化剂 Jacobsen 催化剂 (R,R)-(-)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺氯化锰(III)
MDL NumberMFCD02101664
CAS Number138124-32-0
PubChem Substance ID354335281
Chemical Name Translation雅可布逊晶体
Reaxys-RN15434239
Merck Number5252
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Epoxidation, Privileged Ligands and Complexes, SALENs
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Epoxidation, Privileged Ligands and Complexes, SALENs
  • {SNA} Asymmetric Synthesis,

相关文献及参考

  • 1. Zhang, W. et al. J. Am. Chem. Soc. 112 , 2801, (1990)
  • 2. Zhang, W. Jacobsen, E.N. J. Org. Chem. 56 , 2296, (1991)
  • 3. Jacobsen, E.N. et al. J. Am. Chem. Soc. 113 , 7063, (1991)
  • 4. Lee, N.H. et al. Tetrahedron Lett. 32 , 5055, (1991)
  • 5. Deng, L. Jacobsen, E.N. J. Org. Chem. 57 , 4320, (1992)
  • 6. Senanayake, C.H. et al. Tetrahedron Lett. 37 , 3271, (1996)
  • 7. Senanayake, C.H. et al. Tetrahedron Lett. 36 , 3993, (1995)
  • 8. Adam, W. et al. Tetrahedron 37 , 6531, (1996)
  • 9. J. Am. Chem. Soc. 113 , 7063, (1991)
  • Merck 14 ,5252
  • FT-IR 2 (3), 4564:A / Structure Index 1 , 493:B:8

安全信息

Hazard Codes Xi
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Deprotonation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Epoxidation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. SALENs - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes
  5. PyBOX
  1. Jacobsen Ligand
  2. Manganese
  1. Catalysts
  2. Manganese

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