2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl 2-二环己膦基-2'-(N,N-二甲胺)-联苯

CAS 213697-53-1 MFCD02183572

化学结构图

213697-53-1
SMILES: CN(C)c1ccccc1-c1ccccc1P(C1CCCCC1)C1CCCCC1

化学属性

TSCANo
SolubilityInsoluble
Stability对空气敏感
Mol. FormulaC26H36NP
Mol. Weight394
Appearance white xtl.
Melting Point115-119°C

别名和识别编码

Chemical Name2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl
Alfabeta NameDICYCLOHEXYLPHOSPHINODIMETHYLAMINOBIPHENYL NN22()-----,'
Synonym 2-Dicgclohexylphosphino-2’-(N,N-dimethylamino)biphenyl 2-Dicyclohexylphosphino-2'-(N, 2-二环己基磷-2-(N,N-二甲基氨基)联苯 2-双环己基膦-2'-(N,N-二甲基氨基)联苯,98% DAVEPHOS 2-(Dicyclohexylphosphino)-2'-(N,N-dimethylamino)biphenyl,98%DavePhos 2-二环己基磷-2-（N,N-二甲基氨基）联苯 2-(DICYCLOHEXYLPHOSPHINO)-2'-(DIMETHYLAMINO)BIPHENYL [1,1''-BIPHENYL]-2-AMINE, 2''-(DICYCLOHEXYLPHOSPHINO)-N,N-DIMETHYL- Davep 2-二环己膦基-2′-(N,N-二甲胺)联苯 DavePhos 2-二环己基膦-2′-(N, N-二甲胺基)联苯 2-(N,N-Dimethylamino)-2-(dicyclohexylphosphino)biphenyl 2-二环己膦基-2'-(N,N-二甲胺)-联苯 2-二环己基膦-2'-(N,N-二甲胺)-联苯 2-Dicyclohexylphosphino-2'-(dimethylamino)biphenyl 2-DICYCLOHEXYLPHOSPHINO-2'-(N,N-DIMETHY& 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)- 2-DICYCLOHEXYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL
PubChem Substance ID2734217
Chemical Name Translation2-二环己膦基-2'-(N,N-二甲胺)-联苯
Reaxys-RN8649190
LabNetwork Molecule IDLN00119019
InChIInChI=1S/C26H36NP/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22/h9-12,17-22H,3-8,13-16H2,1-2H3
MDL NumberMFCD02183572
CAS Number213697-53-1
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Buchwald Ligands, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds
  • {SNA} Buchwald Ligands, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Ligands, Phosphine Compounds
  • {SNA} Buchwald Ligands, Buchwald Ligands, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds

产品应用

  • 用于钯催化 C-N 键形成的有效配体；含羟基、酰胺或烯醇酮的芳基卤的胺?化反应。
  • 钯催化 Suzuki 芳基-芳基偶联反应的配体，生成苯并二噁庚英。

安全信息

Warnings AIR SENSITIVE
WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Storage condition 储存温度2-8℃ Air Sensitive
Hazard Codes Xi Xi,Xn

其他信息

  • 上游原料:乙酸乙酯 --> 乙醚 --> 四氢呋喃 --> 二氯甲烷 --> 氢氧化铵 --> 硫酸二甲酯 --> 碘甲烷 --> 镁 --> 三氯化磷 --> 氯化亚铜 --> 二乙胺 --> 环己烷 --> 1,2-二溴乙烷 --> 2-氯苯胺 --> 对溴甲苯 --> 氯代环己烷 --> 溴代环己烷 --> 2-溴氯苯 --> 2-溴苯胺 --> 3,5-二甲基溴苯
  • Sigma Aldrich:213697-53-1(sigmaaldrich)
  • 存储注意事项:空气敏感;氮气保护
  • TCI Shanghai:2-(二环己膦基)-2'-(N,N-二甲胺)联苯 2-(Dicyclohexylphosphino)-2'-(dimethylamino)biphenyl,>;98.0%(LC)(213697-53-1)
  • 检测方法:GC
  • Acros Organics:2-二环己基磷-2-（N,N-二甲基氨基）联苯 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl, 97%(213697-53-1)
  • 敏感性:Air Sensitive
  • 2-二环己膦基-2'-(N,N-二甲胺)-联苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D3389 2-(二环己膦基)-2'-(N,N-二甲胺)联苯 2-(Dicyclohexylphosphino)-2'-(dimethylamino)biphenyl 1G 1270元 2011/04/16 D3389 2-(二环己膦基)-2'-(N,N-二甲胺)联苯 2-(Dicyclohexylphosphino)-2'-(dimethylamino)biphenyl 5G 4830元 2010/06/21 356230050 2-二环己膦基-2'-(N,N-二甲胺)-联苯 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl 97% 5 GR 13361元
  • Alfa Aesar:2-双环己基膦-2'-(N,N-二甲基氨基)联苯,98% 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl, 98%(213697-53-1)
  • 用途二:精细化工原料，医药中间体。
  • 用途一:作为配体，用于Suzuki, Buchwald等偶联反应以及取代反应中
  • MOL 文件:213697-53-1.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Buchwald Ligands Buchwald 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Buchwald Ligands Buchwald 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cross-Coupling 交叉偶联
  4. Basic Phosphine Ligands
  1. Functional Group 官能团索引
  2. phosphine
  1. Buchwald Precatalysts & Ligands
  2. Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Buchwald Precatalysts & Ligands
  2. 96-5500 Buchwald Biaryl Phosphine Ligand Master Kit for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Ligands
  2. 96-5500 Buchwald Biaryl Phosphine Ligand Master Kit for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Phosphine
  2. 96-5500 Buchwald Biaryl Phosphine Ligand Master Kit for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Buchwald Precatalysts & Ligands
  2. 96-5490 Buchwald Biaryl Phosphine Ligand Mini Kit 2 for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Ligands
  2. 96-5490 Buchwald Biaryl Phosphine Ligand Mini Kit 2 for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Phosphine
  2. 96-5490 Buchwald Biaryl Phosphine Ligand Mini Kit 2 for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Ligands
  2. Phosphorus
  3. Buckwad Ligands/偶联C-N键生成

相关产品推荐