4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline 4-氨基苯硼酸频那醇酯
CAS 214360-73-3 MFCD02093721
化学结构图
SMILES: CC1(C)OB(c2ccc(N)cc2)OC1(C)C
化学属性
| Mol. Formula | C12H18BNO2 |
|---|---|
| Mol. Weight | 219.09 |
| Melting Point | 165-169 |
| TSCA | No |
| Appearance | beige pwdr. |
别名和识别编码
| Chemical Name | 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline |
|---|---|
| CAS Number | 214360-73-3 |
| Alfabeta Name | AMINOPHENYLBORONICACIDPINACOLESTER 4- |
| MDL Number | MFCD02093721 |
| Synonym | 4-氨基苯硼酸频哪醇酯 4-(4,4,5,5-四甲基-1,3,2-二氧杂环戊硼烷-2-基)苯胺 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzeneamine 4-Aminophenylboronic acid pinacol ester 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenylamine 2-(4-Aminophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 2-(4-Aminophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzeneamine 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenylamine 4-(4,4,5,5-四甲基-1,3,2-二氧杂环戊硼烷-2-基)苯胺 对氨基苯硼酸频哪醇酯 |
| PubChem Substance ID | 2734620 |
| Reaxys-RN | 9049485 |
| Chemical Name Translation | 4-氨基苯硼酸频那醇酯 |
| LabNetwork Molecule ID | LN00005689 |
| InChI | InChI=1S/C12H18BNO2/c1-11(2)12(3,4)16-13(15-11)9-5-7-10(14)8-6-9/h5-8H,14H2,1-4H3 |
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分类
- Aryl Boronate Esters, Boronate Esters, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents
- {SNA} Aryl Boronate Esters, Boronate Esters, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents
相关文献及参考
- 1. Koenig, M.;et al. , Suzuki-Miyaura cross-coupling reaction on copper-trans-A2B corroles with excellent functional group tolerance Tetrahedron 23th ed., 67 , 4243-4252, (2011) 摘要
- 2. Bhalla, V.; et al. , New Fluorogenic Sensors for Hg2+ Ions: Through-Bond Energy Transfer from Pentaquinone to Rhodamine Inorg. Chem. 4th ed., 51 , 2150-2156, (2012) 摘要
- 3. Arnold, J. S.; Cizio, G. T.; Nguyen, H. M. , Synthesis of a,a-disubstituted aryl amines by rhodium-catalyzed amination of tertiary allylic trichloroacetimidates Org. Lett. 20th ed., 13 , 5576-5579, (2011) 摘要
- 4. Patel, A. B.; et al. , Synthesis of potential antitubercular and antimicrobial s-triazine-based scaffolds via Suzuki cross-coupling reaction Med. Chem. Res. , (2012)
- 5. Bhalla, V.; et al. , Recognition of Adenosine Monophosphate and H2PO4- using Zinc Ensemble of New Hexaphenylbenzene Derivative: Potential Bioprobe and Multichannel Keypad System Org. Lett. 4th ed., 14 , 1012-1015, (2012) 摘要
- 6. Kola, S.; et al., Synthesis and Characterization of a Pyromellitic Diimide-Based Polymer with C- and N-Main Chain Links: Matrix for Solution-Processable n-Channel Field-Effect Transistors ACS Macro Lett. 1st ed., 1 , 136-140, (2012)
- 7. Gawrys, P.; et al. , Alternating copolymers of oligoarylenes and naphthalene bisimides as low band gap semiconductors: Synthesis, electrochemical and spectroelectrochemical behavior Electrochimica Acta 28th ed., 56 , 10464-10472, (2012)
- 8. Luebbers, T.; et al. , Aminothiazoles as γ-secretase modulators Bioorg. Med. Chem. Lett. 21th ed., 21 , 6554-6558, (2012)
- J. Med. Chem. 49 , 3973, (2006) 摘要
安全信息
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P332+P313
- P305+P351+P338+P337+P313
- P302+P352+P332+P313+P362+P364
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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