2-(1,3-Dioxan-2-yl)ethylzinc bromide solution 2-(1,3-二氧杂环己基)乙基溴化锌 溶液

CAS 307531-82-4 MFCD02260128

化学结构图

307531-82-4
SMILES: Br[Zn]CCC1OCCCO1

化学属性

Mol. FormulaC6H11BrO2Zn
Mol. Weight260.44
Density0.982 g/mL at 25 °C
Boiling Point65 °C
TSCANo

别名和识别编码

Chemical Name2-(1,3-Dioxan-2-yl)ethylzinc bromide solution
MDL NumberMFCD02260128
PubChem Substance ID24877971
CAS Number307531-82-4
Synonym 2-(1,3-二氧杂环己基)乙基溴化锌 溶液
Chemical Name Translation2-(1,3-二氧杂环己基)乙基溴化锌 溶液
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分类

  • {SNA} Alkyl, Chemical Synthesis, Organometallic Reagents, Organozinc Halides, Rieke and Organozinc Reagents

安全信息

WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Packing GroupII
UN Number UN3399
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R37 Irritating to respiratory system 刺激呼吸道
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
Storage condition Air Sensitive
Hazard Codes F,C F,Xn
GHS Symbol
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H351 Suspected of causing cancer 怀疑致癌
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P370+P378
  • P403+P235
Signal word Danger

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organozinc Reagents 有机锌试剂
  4. Organozinc Halides 有机锌卤化物
  5. Alkyl - Organozinc Halides
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organozinc Reagents 有机锌试剂
  4. Organozinc Halides 有机锌卤化物
  5. Alkyl - Organozinc Halides

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