Fluoro-N,N,N,N-Tetramethylformamidinium Hexafluorophosphate 四甲基氟代脲六氟磷酸酯

CAS 164298-23-1 MFCD02684443

化学结构图

164298-23-1
SMILES: CN(C)C(F)=[N+](C)C.F[P-](F)(F)(F)(F)F

化学属性

Mol. FormulaC5H12F7N2P
Mol. Weight264
Melting Point104-109
TSCANo

别名和识别编码

Chemical NameFluoro-N,N,N,N-Tetramethylformamidinium Hexafluorophosphate
Synonym 四甲基氟代脲六氟磷酸酯,TFFH TFFH N,N,N',N'-Tetramethylfluoroformamidiniun hexafluorophosphate Fluoro-N,N,N',N'-tetramethylformamidinium hexafluorophosphate
MDL NumberMFCD02684443
PubChem Substance ID87561692
CAS Number164298-23-1
Reaxys-RN7321765
Beilstein Registry Number7321765
Chemical Name Translation四甲基氟代脲六氟磷酸酯
InChIKeyZAVXOOLKAGPJPI-UHFFFAOYSA-N
LabNetwork Molecule IDLN00170430
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分类

  • {SA} Chemical Biology, Chemical Synthesis, Coupling, Fluorination, Fluorination Reagents, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
  • {SNA} Chemical Biology, Chemical Synthesis, Coupling, Fluorination,

产品应用

  • 用于多肽缩合剂。

相关文献及参考

  • 1. T. Hansen, et al., J. Med. Chem. 54 , 858-868, (2011)
  • 2. S. Froelund, et al., J. Med. Chem. 53 , 7441-7451, (2010)
  • 3. T. Hansen, et al., J. Med. Chem. 53 , 595-606, (2010)
  • 4. R. B. Silverman, et al., Bioorg. Med. Chem. 17 , 7593-7605, (2009)
  • 5. M. Jin, et al., Bioorg. Med. Chem. Lett. 21 , 1176-1180, (2011)
  • 6. F. M. Brunel, et al., Nano Lett. 10 , 1093-1097, (2010)

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Storage condition 阴凉干燥处保存。储存温度:2-8°C 0-10 0-10°C
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Coupling - Synthetic Reagents
  4. Phosphonium/Uronium/Formamidinium - Coupling
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Coupling - Synthetic Reagents
  4. Phosphonium/Uronium/Formamidinium - Coupling
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ureas - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Peptide Coupling - Peptide Chemistry
  5. Phosphonium/Uronium/Formamidinium - Peptide Coupling
  1. Functional Group 官能团索引
  2. CO2 derivative (general)

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