N,N’-((1S,2S)-Cyclohexane-1,2-Diyl)Bis(2-(Diphenylphosphino)-1-Naphthamide) (1S,2S)-(-)-N,N’-双(2-二苯基膦基-1-萘酰基)-1,2-环己二胺
CAS 205495-66-5 MFCD02684552
化学结构图
SMILES: O=C(N[C@H]1CCCC[C@@H]1NC(=O)C1=C(C=CC2C=CC=CC=21)P(C1C=CC=CC=1)C1C=CC=CC=1)C1=C(C=CC2C=CC=CC=21)P(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Melting Point | 232-237 °C |
|---|---|
| Mol. Formula | C52H44N2O2P2 |
| Appearance | off-white pwdr. |
| Mol. Weight | 791 |
别名和识别编码
| Chemical Name | N,N’-((1S,2S)-Cyclohexane-1,2-Diyl)Bis(2-(Diphenylphosphino)-1-Naphthamide) |
|---|---|
| Synonym | (S,S)-DACH-萘基 Trost 配体 (1S,2S)-(–)-1,2-二氨基环己烷-N,N′-双(2-二苯基膦-1-萘酰基) |
| Chemical Name Translation | (1S,2S)-(-)-N,N’-双(2-二苯基膦基-1-萘酰基)-1,2-环己二胺 |
| PubChem Substance ID | 329761527 |
| MDL Number | MFCD02684552 |
| CAS Number | 205495-66-5 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Trost Ligands
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Trost Ligands
相关文献及参考
- 1. Trost, B.M. et al. Chem. Rev. 96 , 395, (1996) 摘要
- 2. Trost, B.M. et al. Chem. Rev. 103 , 2921, (2003) 摘要
- 3. Trost, B.M. et al. J. Am. Chem. Soc. 124 , 11616, (2004)
- 4. Trost, B.M. et al. Aldrichimica Acta 40 , 59, (2007)
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