(1R,2R)-(-)-[1,2-Cyclohexanediamine-N,N’-Bis(3,5-Di-Tertbutylsalicylidine)]Chromium(III) Chloride (1R,2R)-(-)-[1,2-环己二胺-N,N’-双(3,5-二-叔丁基水杨烷基)]氯化铬(III)

CAS 219143-92-7 MFCD02684555

化学结构图

219143-92-7
SMILES: CC(C)(C)c1cc2c(c(C(C)(C)C)c1)O[Cr](Cl)Oc1c(cc(C(C)(C)C)cc1C(C)(C)C)C=N[C@@H]1CCCC[C@H]1N=C2

化学属性

Mol. FormulaC36H52ClCrN2O2
Mol. Weight632.26
Melting Point250-255 °C(lit.)

别名和识别编码

Chemical Name(1R,2R)-(-)-[1,2-Cyclohexanediamine-N,N’-Bis(3,5-Di-Tertbutylsalicylidine)]Chromium(III) Chloride
MDL NumberMFCD02684555
PubChem Substance ID24877849
CAS Number219143-92-7
Synonym (R,R)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺氯化铬(III) (S,S)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺氯化铬(III)
Chemical Name Translation(1R,2R)-(-)-[1,2-环己二胺-N,N’-双(3,5-二-叔丁基水杨烷基)]氯化铬(III)
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Cycloaddition, Privileged Ligands and Complexes, SALENs
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Cycloaddition, Privileged Ligands and Complexes, SALENs

相关文献及参考

  • 2. Ma, D.-Y.; et al., Dynamic Supramolecular [(Salen)CrCl] Complexes as Efficient Catalysts for Ring Opening of Epoxides ChemCatChem 2 , 629-632, (2010)
  • 1. Hao, Z.; et al., A readily synthesized cyclic pyrrolysine analogue for site-specific protein "click" labeling Chem. Commun. 47 , 4502-4504, (2011)
  • 4. Kowalczyk, R.; et al., Asymmetric nitroaldol reaction catalyzed by a chromium(III)-salen system Tetrahedron Asymmetry 18 , 2581-2586, (2007)
  • 3. Bryliakov, K. P.; Talsi, E. P., CrIII(salen)Cl Catalyzed Asymmetric Epoxidations: Insight into the Catalytic Cycle Inorg. Chem. 42 , 7258-7265, (2003)

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Signal word Warning
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Cycloaddition - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. SALENs - Privileged Ligands and Complexes

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