2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine, polymer-bound 2-叔丁基亚氨基-2-二乙基氨基-1,3-二甲基全氢-1,3,2-二氮杂磷，聚合物键合型

CAS N/A MFCD03095934

化学结构图

N/A
SMILES:

别名和识别编码

Synonym BEMP 树脂 2-叔丁基亚氨基-2-二乙基氨基-1,3-二甲基全氢-1,3,2-二氮杂磷，聚合物键合型
MDL NumberMFCD03095934
PubChem Substance ID24878163
Chemical Name2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine, polymer-bound
Chemical Name Translation2-叔丁基亚氨基-2-二乙基氨基-1,3-二甲基全氢-1,3,2-二氮杂磷，聚合物键合型
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分类

  • {SNA} Acids & Bases, Bases, Chemical Synthesis, Phosphazene Bases, Solid Supported Synthesis, Specialty Synthesis, Supported Reagents, Synthetic Reagents
  • {SNA} Bases, Chemical Synthesis, Phosphazene Bases, Solid Supported Synthesis, Specialty Synthesis,

相关文献及参考

  • 1. Gregory L. Adams et al., A convenient 'catch and release' synthesis of fused 2-alkylthio-pyrimidinones mediated by polymer-bound BEMP. Tetrahedron Lett. 44 , 5041-5045, (2003)
  • Ying Wang et al., Rapid and Efficient Synthesis of 1,2,4-Oxadiazoles Utilizing Polymer-Supported Reagents under Microwave Heating. Org. Lett. 7 , 925-928, (2005) 摘要
  • Jose Luis Chiara, Lourdes Encinas and Beatriz Diaz, A study of polymer-supported bases for the solution phase synthesis of glycosyl trichloroacetimidates. Tetrahedron Lett. 46 , 2445-2448, (2005)

安全信息

Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
WGK Germany3
GHS Symbol
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Hazard Codes C
Signal word Danger
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R34 Causes burns 会导致灼伤

系列性分类

  1. Chemical Synthesis 化学合成
  2. Specialty Synthesis 特殊合成技术
  3. Solid Supported Synthesis - Specialty Synthesis
  4. Supported Reagents - Solid Supported Synthesis
  5. Bases - Supported Reagents

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