Tris[N,N-Bis(Trimethylsilyl)Amide]Neodymium(Iii) 三［N,N-双（三甲基硅烷）胺］钕(III)

CAS 148274-47-9 MFCD03427089

化学结构图

148274-47-9
SMILES: C[Si](C)(C)N([Nd](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

化学属性

Mol. FormulaNd(N(Si(CH3)3)2)3
Mol. Weight625.39
Melting Point156-159 °C(lit.)
TSCANo

别名和识别编码

Chemical NameTris[N,N-Bis(Trimethylsilyl)Amide]Neodymium(Iii)
Synonym Neodymium(III) tris[N,N-bis(trimethylsilyl)amide] 三[N,N-双(三甲基硅烷)胺]钕(III) 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine neodymium(III) salt
CAS Number148274-47-9
PubChem Substance ID24878980
MDL NumberMFCD03427089
Chemical Name Translation三［N,N-双（三甲基硅烷）胺］钕(III)
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分类

  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Neodymium, Vapor Deposition Precursors
  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Neodymium, Vapor Deposition Precursors, 材料科学
  • {SA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Neodymium, Vapor Deposition Precursors

相关文献及参考

  • 1. Y. A. Efimova, et al., Russ. J. Gen. Chem. 79 , 1641-1644, (2009)
  • 2. M. Veith, et al., Eur. J. Inorg. Chem. 6 , 879-889, (2010)
  • 3. H. F. Yuen and T. J. Marks, Organometallics 28 , 2423-2440, (2009)
  • 4. H. He, et al., Aust. J. Chem. 57 , 803-810, (2004)
  • 5. A. Fischbach, et al., Organometallics 25 , 1626-1642, (2006)
  • 6. P. L. Arnold and S. T. Liddle, Chem. Commun. 45 , 5638-5640, (2005)

安全信息

GHS Symbol
WGK Germany3
Hazard Codes F,C
Hazard statements
  • H228 Flammable solid 易燃固体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P422 Store contents under… 存储目录在…之下。
  • P231+P232
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
UN Number UN3396
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
  • R34 Causes burns 会导致灼伤
Storage condition Moisture Sensitive
Packing GroupII

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Neodymium - Catalysis and Inorganic Chemistry
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Vapor Deposition Precursors for Neodymium Thin Films
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rare-Earth Metals 稀土金属化合物

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