[1,1'-Bis(diphenylphosphino)ferrocene]tetracarbonyltungsten(0) [1,1′-双(二苯基膦)二茂铁]四羰基钨(0)

CAS 67292-26-6 MFCD03427160

化学结构图

67292-26-6
SMILES: [Fe].[W].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=CC=C1P(C1C=CC=CC=1)[C]1[CH][CH][CH][CH]1.C1=CC=CC=C1P(C1C=CC=CC=1)[C]1[CH][CH][CH][CH]1 |^1:23,24,25,26,27,41,42,43,44,45|

化学属性

Mol. Formula(CO)4W(P(C6H5)2C5H4)2Fe
Mol. Weight850.26
Melting Point220 °C (dec.)(lit.)
TSCANo

别名和识别编码

Chemical Name[1,1'-Bis(diphenylphosphino)ferrocene]tetracarbonyltungsten(0)
MDL NumberMFCD03427160
CAS Number67292-26-6
Synonym W(dppf)(CO)4 [1,1′-双(二苯基膦)二茂铁]四羰基钨(0)
PubChem Substance ID24879172
Chemical Name Translation[1,1′-双(二苯基膦)二茂铁]四羰基钨(0)
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Tungsten

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S4 Keep away from living quarters 远离生活区;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
Packing GroupIII
UN Number UN3466
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
Storage condition Air Sensitive
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

系列性分类


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