(+)-1 2-Bis((2R 5R)-2 5-Dimethylphospholano)Ethane(Cyclooctadiene)Rhodium (I) Tetrafluoroborate (R R)-ME-Bpe-RH 1,2-双((2R,5R)-2,5-二甲基磷)乙烷(环辛二烯)四氟硼酸铑(I)
CAS 305818-67-1 MFCD05818671
化学结构图
SMILES: C1=C\CC/C=C\CC/1.C[C@@H]1CC[C@@H](C)P1CCP1[C@H](C)CC[C@H]1C.F[B-](F)(F)F.[Rh]
化学属性
| Mol. Weight | 556.21 |
|---|---|
| Mol. Formula | C22H40BF4P2Rh |
别名和识别编码
| PubChem Substance ID | 16218294 |
|---|---|
| CAS Number | 305818-67-1 |
| Chemical Name | (+)-1 2-Bis((2R 5R)-2 5-Dimethylphospholano)Ethane(Cyclooctadiene)Rhodium (I) Tetrafluoroborate (R R)-ME-Bpe-RH |
| Chemical Name Translation | 1,2-双((2R,5R)-2,5-二甲基磷)乙烷(环辛二烯)四氟硼酸铑(I) |
| Synonym | 1,2-双[(2R,5R)-2,5-(二甲基磷]乙烷(环辛二烯)四氟硼酸铑(I) |
| InChI | InChI=1S/C14H28P2.C8H12.BF4.Rh/c1-11-5-6-12(2)15(11)9-10-16-13(3)7-8-14(16)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11-14H,5-10H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t11-,12-,13-,14-;;;/m1.../s1 |
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
相关文献及参考
- 1. Fox, M. E.; et al., Large-Scale Synthesis of a Substituted D-Phenylalanine Using Asymmetric Hydrogenation Org. Process Res. Dev. 15 , 1163-1171, (2011)
- 2. Benhaim, C.; et al., Enantioselective Synthesis of β-Trifluoromethyl α-Amino Acids Org. Lett. 12 , 2008-2011, (2010)
- 3. Fernandez, E.; et al., Rationally designed improvement of the bis(phospholano)ethane ligand for asymmetric hydrogenation leads to a reappraisal of the factors governing the enantioselectivity of Duphos catalysts Chem. Commun. , 1663-1664, (2000)
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P304+P340
- P305+P351+P338
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
京ICP备2020036287号