Di-mu-Bromobis(tri-tert-butylphosphine)dipalladium (三叔丁基膦)溴化钯(I) 二聚物

CAS 185812-86-6 MFCD04114019

化学结构图

185812-86-6
SMILES: Br[Pd].Br[Pd].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C

化学属性

SolubilitySoluble in benzene and toluene
TSCANo
Mol. FormulaPd2Br2[P(C4H9)3]2
Mol. Weight777
Appearance dark-green xtl.
Stabilityair sensitive, moisture sensitive, store cold

别名和识别编码

Chemical NameDi-mu-Bromobis(tri-tert-butylphosphine)dipalladium
Synonym 三特丁基膦溴化钯 Palladium(I) tri-tert-butylphosphine bromide dimer
PubChem Substance ID24885391
Chemical Name Translation(三叔丁基膦)溴化钯(I) 二聚物
MDL NumberMFCD04114019
CAS Number185812-86-6
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R14 Reacts violently with water 遇水会猛烈反应
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Air Sensitive
WGK Germany3
GHS Symbol
Precautionary statements
  • P222 Do not allow contact with air. 不要与空气接触。
  • P422 Store contents under… 存储目录在…之下。
  • P231+P232
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes F,C

系列性分类


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