(R)-Tol-SDP (R)-Tol-SDP
CAS 528521-87-1 MFCD08459345
化学结构图
SMILES: CC1C=CC(=CC=1)P(C1=CC=CC2CCC3(CCC4C=CC=C(C3=4)P(C3C=CC(C)=CC=3)C3C=CC(C)=CC=3)C=21)C1C=CC(C)=CC=1
化学属性
| Density | 1.422 |
|---|---|
| Mol. Formula | C45H42P2 |
| Mol. Weight | 645 |
| Appearance | white solid |
| Stability | air sensitive |
| Melting Point | 150-152°C |
别名和识别编码
| Chemical Name | (R)-Tol-SDP |
|---|---|
| Synonym | (R)-(+)-7,7′-双[二(4-甲苯基)膦基]-2,2′,3,3′-四氢-1,1′-螺二茚 (R)-7,7′-双[二(对甲基苯基)膦基]-1,1′-螺二氢茚 (S)-(-)-7,7′-双[二(4-甲苯基)膦基]-2,2′,3,3′-四氢-1,1′-螺二茚 (S)-(-)-7,7′-双[二(4-甲苯基)膦基]-2,2′,3,3′-四氢-1,1′-螺二茚 (S)-(-)-7,7′-双[二(对甲苯基)膦基]-1,1′-螺二氢茚 (S)-(-)-7,7′-双[二(对甲苯基)膦基]-1,1′-螺二氢茚 |
| EC Number | 250-023-7 |
| Beilstein Registry Number | 2384789 |
| Chemical Name Translation | (R)-Tol-SDP |
| PubChem Substance ID | 329762235 |
| MDL Number | MFCD08459345 |
| CAS Number | 528521-87-1 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Spiro Ligands
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Spiro Ligands
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
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