Bis(2,2,6,6-tetramethylpiperidinyl)zinc 双(2,2,6,6-四甲基哌啶基)锌

CAS N/A MFCD11656062

化学结构图

N/A
SMILES: CC1(C)CCCC(C)(C)N1[Zn]N1C(C)(C)CCCC1(C)C

化学属性

Mol. FormulaC18H36N2Zn
Mol. Weight345.88
Density0.877 g/mL at 25 °C

别名和识别编码

Chemical NameBis(2,2,6,6-tetramethylpiperidinyl)zinc
Synonym Zn(tmp)2 双(2,2,6,6-四甲基哌啶基)锌
MDL NumberMFCD11656062
Chemical Name Translation双(2,2,6,6-四甲基哌啶基)锌
PubChem Substance ID329761924
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分类

  • {SNA} Chemical Synthesis, Dialkylzincs, Organometallic Reagents, Rieke and Organozinc Reagents

安全信息

Hazard Codes F,Xn
WGK Germany3
Precautionary statements
  • P301+P310
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
Signal word Danger
Safety Statements
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
GHS Symbol
Risk Statements
  • R11 Highly flammable 非常易燃
  • R38 Irritating to skin 刺激皮肤
  • R48/20
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organozinc Reagents 有机锌试剂
  4. Dialkylzincs - Rieke® and Organozinc Reagents

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