2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex 2,2,6,6-四甲基哌啶基氯化镁氯化锂复合物
CAS 898838-07-8 MFCD12546030
化学结构图
SMILES: CC1(C)CCCC(C)(C)N1[Mg]Cl.[Cl-].[Li+]
化学属性
| Mol. Formula | C9H18Cl2LiMgN |
|---|---|
| Mol. Weight | 242 |
| Density | 0.96 |
| Danger-Level | - |
| pH | -:- |
| Redox | - |
别名和识别编码
| Chemical Name | 2,2,6,6-Tetramethylpiperidinylmagnesium Chloride lithium Chloride |
|---|---|
| MDL Number | MFCD12546030 |
| Synonym | TMPMgCl·LiCl 2,2,6,6-四甲基哌啶基氯化镁氯化锂复合物 溶液 |
| Chemical Name Translation | 2,2,6,6-四甲基哌啶基氯化镁氯化锂复合物 |
| PubChem Substance ID | 329762048 |
| CAS Number | 898838-07-8 |
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分类
- {SNA} Chemical Synthesis, Grignard Reagents, Heteroaryl, Organometallic Reagents
- {SNA} 25mL Sure/Seal Reagents, Chemical Synthesis, Grignard Reagents, Heteroaryl, Organometallic Reagents
相关文献及参考
安全信息
GHS Symbol
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P370+P378
- P403+P235
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H302 Harmful if swallowed 吞食有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H351 Suspected of causing cancer 怀疑致癌
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R11 Highly flammable 非常易燃
- R14 Reacts violently with water 遇水会猛烈反应
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R34 Causes burns 会导致灼伤
- R37 Irritating to respiratory system 刺激呼吸道
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
- R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
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