N-Isopropyl-N-Phenyl-1,4-Phenylenediamine N-异丙基-N-苯基-对-苯二胺

CAS 101-72-4 MFCD00026348

化学结构图

101-72-4
SMILES: CC(C)Nc1ccc(Nc2ccccc2)cc1

化学属性

Mol. FormulaC15H18N2
Mol. Weight226.32
Melting Point72-76 °C
Boiling Point161 °C at 760 mmHg
Solubility<0.1 G/100 ML AT 18 ºC
Density1.00
Flash Point198°C(lit.)
TSCAYes

别名和识别编码

Chemical NameN-Isopropyl-N-Phenyl-1,4-Phenylenediamine
MDL NumberMFCD00026348
CAS Number101-72-4
EC Number202-969-7
Synonym N1-Isopropyl-N4-phenylbenzene-1,4-diamine {LY} N1-Isopropyl-N4-phenylbenzene-1,4-diamine {} {LY} N1-Isopropyl-N4-phenylbenzene-1,4-diamine {} {} {LY} N1-Isopropyl-N4-phenylbenzene-1,4-diamine {} {} {} {LY} N1-Isopropyl-N4-phenylbenzene-1,4-diamine {} {} {} {} {LY} N1-Isopropyl-N4-phenylbenzene-1,4-diamine {} {} {} {} {} {LY} N1-Isopropyl-N4-phenylbenzene-1,4-diamine {} {} {} {} {} {} {LY} N1-Isopropyl-N4-phenylbenzene-1,4-diamine {} {} {} {} {} {} {} {LY} N1-Isopropyl-N4-phenylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {LY} N1-Isopropyl-N4-phenylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {} {LY} N1-Isopropyl-N4-phenylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {} {} {LY} N1-Isopropyl-N4-phenylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {} {} {} {LY} N1-Isopropyl-N4-phenylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1-Isopropyl-N4-phenylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1-Isopropy
Reaxys-RN2213195
PubChem Substance ID7573
Chemical Name TranslationN-异丙基-N-苯基-对-苯二胺
Beilstein Registry Number2213195
Wiswesser Line Notation1YMR DMR
LabNetwork Molecule IDLN00238001
InChIInChI=1S/C15H18N2/c1-12(2)16-14-8-10-15(11-9-14)17-13-6-4-3-5-7-13/h3-12,16-17H,1-2H3
Canonical SMILESCC(C)NC1=CC=C(C=C1)NC2=CC=CC=C2
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相关文献及参考

  • Antioxidant for rubbers.

安全信息

RTECSST2650000
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Packing GroupIII
UN Number 3077 UN3077
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R50/53
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Air Sensitive {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from
Signal word Warning
Hazard statements
  • H302 Harmful if swallowed 吞食有害
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P301+P312+P330
  • P302+P350
  • P302+P352+P333+P313+P362+P364
  • P305+P351+P338+P337+P313
  • P308+P313
  • P337+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard Codes 9
Hazard Class9
GHS Symbol 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1122 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KOKABN Kobunshi Kako.  Polymer Applications.  (Kobunshi Kankokai, Chiekoin
   Maruta-machi Kundaru, Kamigyo-ku, Kyoto 602, Japan)  V.13-    1964-
   Volume(issue)/page/year: 26,438,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 720 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IPSTB3 International Polymer Science and Technology.  (Rapra Technology
   Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year:
   3,93,1976

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >7500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IPSTB3 International Polymer Science and Technology.  (Rapra Technology
   Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year:
   3,93,1976

WGK Germany3

其他信息

  • 图谱信息:橡胶防老剂 4010NA(101-72-4)红外图谱(IR2) 橡胶防老剂 4010NA(101-72-4)红外图谱(IR1) 橡胶防老剂 4010NA(101-72-4)核磁图( 1 HNMR) 橡胶防老剂 4010NA(101-72-4)核磁图( 13 CNMR) 橡胶防老剂 4010NA(101-72-4)质谱(MS)
  • TCI Shanghai:4-异丙氨基二苯胺 4-Isopropylaminodiphenylamine,>;95.0%(T)(101-72-4)
  • 用途二:天然橡胶、合成橡胶及胶乳的通用型优良防老剂，对臭氧、屈挠龟裂的防护性能特佳，也是热、氧、光等和一般老化的优良防老剂。常用于制造承受动态的静态应力较高的制品，如飞机和汽车轮胎、自行车外胎、电缆、胶管、胶带、胶辊及其他工业橡胶制品。该品有污染性，不宜用于浅色橡胶制品。
  • Sigma Aldrich:101-72-4(sigmaaldrich)
  • 橡胶防老剂 4010NA价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0327 4-异丙氨基二苯胺 4-Isopropylaminodiphenylamine 500G 714元 2014/06/02 P0327 4-异丙氨基二苯胺 4-Isopropylaminodiphenylamine 25G 114元 2010/05/25 B25378 N-异丙基-N'-苯基-对-苯二胺, 95% N-Isopropyl-N'-phenyl-p-phenylenediamine, 95% 250g 452元
  • 方法一:对氨基二苯胺（即RT倍司）与丙酮在铜-铬催化剂存在下，于160-165℃、氢气压力5-6MPa条件下反应。反应物趁热滤去催化剂，经冷冻结晶、过滤、干燥，即得成品。过滤母液可通过蒸馏回收异丙醇。原料消耗（kg/t）RT倍司 875丙酮 420催化剂 12氢气 60
  • Alfa Aesar:N-异丙基-N'-苯基-对-苯二胺,95% N-Isopropyl-N'-phenyl-p-phenylenediamine, 95%(101-72-4)
  • MOL 文件:101-72-4.mol
  • 上游原料:碳酸钾 --> 丙酮 --> 异丙醇 --> 氢 --> 氨基苯 --> 对氨基二苯胺 --> 亚铬酸铜
  • MSDS 信息:防老剂4010NA(101-72-4).msds
  • 用途一:天然橡胶、合成橡胶及胶乳用通用型优良防老剂，对臭氧和屈挠疲劳老化有卓越的防护效能
  • 外观性质:紫灰色片状结晶。
  • Hazard Note:Irritant

系列性分类

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