Ethyl Phenylcarbamate 苯基氨基甲酸乙酯

CAS 101-99-5 MFCD00026806

化学结构图

101-99-5
SMILES: CCOC(=O)Nc1ccccc1

化学属性

Mol. FormulaC9H11NO2
Mol. Weight165.19
Boiling Point238.0±0.0 °C at 760 mmHg
Melting Point53 °C
Density1.106
Refractive index1.5375
TSCAYes
Flash Point79.2±18.7 °C

别名和识别编码

Chemical NameEthyl Phenylcarbamate
CAS Number101-99-5
Alfabeta NamePHENYLURETHANE N-
MDL NumberMFCD00026806
Synonym Ethyl phenylcarbamate {LY} Ethyl phenylcarbamate {} {LY} Ethyl phenylcarbamate {} {} {LY} Ethyl phenylcarbamate {} {} {} {LY} Ethyl phenylcarbamate {} {} {} {} {LY} Ethyl phenylcarbamate {} {} {} {} {} {LY} Ethyl phenylcarbamate {} {} {} {} {} {} {LY} Ethyl phenylcarbamate {} {} {} {} {} {} {} {LY} Ethyl phenylcarbamate {} {} {} {} {} {} {} {} {LY} Ethyl phenylcarbamate {} {} {} {} {} {} {} {} {} {LY} Ethyl phenylcarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl phenylcarbamate {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl phenylcarbamate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl phenylcarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl phenylcarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl phenylcarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl phenylcarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number202-995-9
Merck Number7320
Beilstein Registry Number1942785
Chemical Name Translation苯基氨基甲酸乙酯
Reaxys-RN1942785
PubChem Substance ID7591
Wiswesser Line Notation2OVMR
LabNetwork Molecule IDLN00159638
InChIInChI=1S/C9H11NO2/c1-2-12-9(11)10-8-6-4-3-5-7-8/h3-7H,2H2,1H3,(H,10,11)
Canonical SMILESCCOC(NC1=CC=CC=C1)=O
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; carbamate; 1fragment

相关文献及参考

  • Short: III/10a Title: Structure Data of Organic Crystals: C ... C 15 Author: Schudt-Weitz, G.; Strell, I. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/10a Year: 1985 ISBN: 3-540-07834-7 ISBN: 978-3-540-07834-0 Internet Resource: DOI:10.1007/b19984 RefComment: XXII, 634 pages. Hardcover Abstract: The volume includes an alphabetical index of all substances and a separate "ring index" with all cyclic compounds.
  • Short: IV/16 Title: Surface tension of pure liquids and binary mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/16 Year: 1997 Keyword: organic compounds; surface tension; liquids; mixtures ISBN: 3-540-63276-X ISBN: 978-3-540-63276-4 Internet Resource: DOI:10.1007/b60566 RefComment: VII, 439 pages.
  • Short: IV/18B Title: Viscosity of Pure Organic Liquids and Binary Liquid Mixtures: Pure Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/18B Year: 2001 Keyword: organic compounds; viscosity; liquids; mixtures Internet Resource: DOI:10.1007/b68240 RefComment: VII, 409 pages.
  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.
  • Short: IV/20C Title: Vapor Pressure and Antoine Coefficients for Nitrogen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20C Year: 2001 Keyword: organic compounds; vapor pressure ISBN: 3-540-41060-0 ISBN: 978-

安全信息

Warnings IRRITANT
RTECSFD8925000
Hazard Codes Xn
Safety Statements
Risk Statements
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 20 gm/kg/2W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1947-  Volume(issue)/page/year:
   9,177,1955

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 72 gm/kg/15W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1947-  Volume(issue)/page/year:
   10,363,1956

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 350 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBTXAC "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co.,
   1956-59  Volume(issue)/page/year: 5,45,1959

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
REFERENCE :
   HDTU** "Pharmakologische Prufung von Analgetika, Dissertation," Herrlen, G.,
   Pharmakologischen Institut der Universitat Tubingen, Fed. Rep. Ger., 1933 
   Volume(issue)/page/year: -,-,1933

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Vascular - regional or general arteriolar or venous dilation
REFERENCE :
   BJPCAL British Journal of Pharmacology and Chemotherapy.  (London, UK)
   V.1-33, 1946-68.  For publisher information, see BJPCBM.
   Volume(issue)/page/year: 7,142,1952

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBTXAC "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co.,
   1956-59  Volume(issue)/page/year: 5,45,1959

Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Storage condition

其他信息

  • Alfa Aesar:N-二苯尿烷,98% N-Phenylurethane, 98%(101-99-5)
  • 类别:农药
  • 毒性分级:中毒
  • 储运特性:库房低温通风干燥
  • 急性毒性:腹腔-小鼠 LD50: 350 毫克/公斤; 静脉-小鼠 LD50: 400 毫克/公斤
  • 下游产品:磺胺苯吡唑 --> 阿莫沙平
  • 可燃性危险特性:热分解排出有毒氮氧化物烟雾
  • N-二苯尿烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0165 苯基尿烷 Phenylurethane 500G 2530元 2014/06/02 P0165 苯基尿烷 Phenylurethane 25G 293元 2014/06/02 P1090 苯胺甲酸乙酯 Phenylurethane 25G 416元
  • Sigma Aldrich:101-99-5(sigmaaldrich)
  • 灭火剂:水, 二氧化碳, 泡沫, 干粉
  • 图谱信息:N-二苯尿烷(101-99-5)核磁图( 1 HNMR) N-二苯尿烷(101-99-5)Raman光谱 N-二苯尿烷(101-99-5)核磁图( 13 CNMR) N-二苯尿烷(101-99-5)质谱(MS) N-二苯尿烷(101-99-5)红外图谱(IR1) N-二苯尿烷(101-99-5)红外图谱(IR2)
  • Acros Organics:苯基氨基甲酸乙酯 Ethyl carbanilate, 98%(101-99-5)
  • MOL 文件:101-99-5.mol
  • TCI Shanghai:N-苯基尿烷 Phenylurethane,>;99.0%(GC)(101-99-5)

系列性分类


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