4-Methyl-2-Pentyl Acetate 乙酸4-甲基-2-戊酯

CAS 108-84-9 MFCD00053723

化学结构图

108-84-9
SMILES: CC(C)CC(C)OC(C)=O

化学属性

Mol. FormulaC8H16O2
Mol. Weight144.21
Refractive index1.4000 to 1.4020
Boiling Point144°C
Flash Point45°C(lit.)
Solubility不溶于水,溶于乙醇等多数有机溶剂。
Density0,86 g/cm3

别名和识别编码

Chemical Name4-Methyl-2-Pentyl Acetate
MDL NumberMFCD00053723
CAS Number108-84-9
Synonym 1,3-DIMETHYLBUTYL ACETATE 1,3-Dimethylbutyl acetate 1,3-Dimethylbutyl ethanoate 1,3-Dimethylbutylacetat 1,3-Dimethylbutylester kyseliny octove 1,3-dimethylbutyl 1,3-dimethylbutyl acetate 1,3-dimethylbutylesterkyselinyoctove 2-Pentanol, 4-methyl-, acetate 2-Pentanol,4-methyl-,acetate 4-METHYL-2-PENTANOL ACETATE 4-METHYL-2-PENTYL ACETATE 4-Methyl-2-amyl acetate 4-Methyl-2-pentanol acetate 4-Methyl-2-pentanol, acetate 4-Methyl-2-pentyl acetate 4-Methyl-2-pentylacetat 4-Methylpent-2-yl acetate 4-methyl-2-pentanoacetate 4-methyl-2-pentyl acetate 4-甲基-2-戊醇乙酸酯 ACETIC ACID 1,3-DIMETHYLBUTYL ESTER ACETIC ACID 4-METHYL-2-PENTYL ESTER Acetic acid, 1,3-dimethylbutyl ester Essigsäure-4-methyl-2-pentylester MAAC MAAc METHYL AMYL ACETATE Methyl amyl acetate Methyl-amyl-acetate- Methylamyl acetate Methylisoamyl acetate Methylisobutylcarbinol acetate Methylisobutylcarbinyl acetate Methylisobutylcarbinylacetat Secondary hexyl acetate acetic acid 1,3-dimethyl-butyl ester methylisoamylacetate methylisobutylcarbinolacetate sec-Hexyl acetate sek.Isohexylester kyseliny octove {} {} {uni_hamburg} 乙酸4-甲基-2-戊酯 乙酸仲己酯
EC Number203-621-7
Reaxys-RN1749848
PubChem Substance ID87562805
Chemical Name Translation乙酸4-甲基-2-戊酯
Wiswesser Line Notation1Y1&1Y1&OV1
Beilstein Registry Number1749848
LabNetwork Molecule IDLN01740053
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分类

  • {SNA} Building Blocks, C8 to C9, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • {uni_hamburg} no charge; ester; racemate; 1fragment

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.

安全信息

GHS Symbol
WGK Germany2
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P302+P352+P332+P313+P362+P364
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+P361+P353
  • P403+P233
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P304+P340+P312
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P305+P351+P338+P337+P313
  • P241+P242+P243
  • P405 Store locked up. 上锁保管。
  • P233 Keep container tightly closed. ?保持容器密闭。
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
RTECSSA7525000
Signal word Warning
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Hazard Codes Xi
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37 Irritating to respiratory system 刺激呼吸道
Packing GroupIII
UN Number 1233 3272
Hazard Class3
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6160 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 7/28/1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >20 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 7/28/1966

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 100 ppm
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - effect, not otherwise
   specified
   Sense Organs and Special Senses (Eye) - conjunctive irritation
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 28,262,1946

其他信息

  • 灭火剂:干粉、二氧化碳、泡沫、1211灭火剂
  • MSDS 信息:乙酸仲己酯(108-84-9).msds
  • 刺激数据:皮肤- 兔子 500 毫克 轻度; 眼睛- 兔子 500 毫克/ 24小时 轻度
  • 毒性分级:低毒
  • 外观性质:无色液体,有芳香气味。
  • TCI Shanghai:4-甲基-2-戊基乙酸酯 4-Methyl-2-pentyl Acetate,>;98.0%(GC)(108-84-9)
  • 类别:易燃液体
  • 急性毒性:口服- 大鼠 LD50: 6160 毫克/ 公斤
  • 储运特性:库房通风低温干燥; 与氧化剂分开存放
  • Sigma Aldrich:108-84-9(sigmaaldrich)
  • 乙酸4-甲基-2-戊酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A1347 乙酸4-甲基-2-戊酯 4-Methyl-2-pentyl Acetate 25G 1690元
  • 爆炸物危险特性:与空气混合可爆; 对皮肤,角膜有腐蚀性
  • MOL 文件:108-84-9.mol
  • 图谱信息:乙酸4-甲基-2-戊酯(108-84-9)红外图谱(IR1) 乙酸4-甲基-2-戊酯(108-84-9)核磁图( 1 HNMR) 乙酸4-甲基-2-戊酯(108-84-9)核磁图( 13 CNMR) 乙酸4-甲基-2-戊酯(108-84-9)质谱(MS)
  • 可燃性危险特性:遇明火、高温、氧化剂较易燃; 燃烧产生刺激烟雾
  • 职业标准:TWA 300 毫克/ 立方米

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