CAS 108-93-0 MFCD00003855-Cyclohexanol 环己醇 -LabNovo

Cyclohexanol 环己醇

CAS 108-93-0 MFCD00003855

化学结构图

SMILES: [O]c1ccccc1

化学属性

Mol. Formula	C6H12O
Mol. Weight	100.16
Density	0.948
Refractive index	n20/D 1.465(lit.)
Flash Point	68°C
TSCA	Yes
Boiling Point	160-161°C at 760 mmHg
Melting Point	20-22°C
Autoignition Point	572 °F
Vapor Density	3.5 (vs air)
Vapor Pressure	0.98 mmHg ( 25 °C)
Solubility	微溶于水，可混溶于乙醇、乙醚、苯、乙酸乙酯、二硫化碳、油类等。
Stability	对湿度敏感

别名和识别编码

Chemical Name	Cyclohexanol
CAS Number	108-93-0
EC Number	203-630-6
Beilstein Registry Number	906744
MDL Number	MFCD00003855
Synonym	1-Cyclohexanol {LY} 1-Cyclohexanol {} {LY} 1-Cyclohexanol {} {} {LY} 1-Cyclohexanol {} {} {} {LY} 1-Cyclohexanol {} {} {} {} {LY} 1-Cyclohexanol {} {} {} {} {} {LY} 1-Cyclohexanol {} {} {} {} {} {} {LY} 1-Cyclohexanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexanol {} {} {} {} {} {} {} {} {LY} 1-Cyclohexanol {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexanol {} {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexanol {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexanol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexanol {} {} {} {} {}
Merck Number	14,2725
PubChem Substance ID	24846712
Chemical Name Translation	环己醇
Wiswesser Line Notation	L6TJ AQ
LabNetwork Molecule ID	LN00193182
Canonical SMILES	OC1CCCCC1

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产品应用

比色法测定钼和铼，以苯肼测定铝。以8-羰基喹啉或以碘化物测定铋时作溶剂，以提取带色物质。橡胶、树脂和硝化棉溶剂。杀虫剂。

安全信息

Signal word

GHS Symbol

WGK Germany1

Safety Statements

Risk Statements

R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

RTECSGV7875000

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} { {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} { {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperatu

Hazard Codes Xn

Hazard statements

H332 Harmful if inhaled 吸入有害
H315 Causes skin irritation 会刺激皮肤
H302 Harmful if swallowed 吞食有害
H335 May cause respiratory irritation 可能导致呼吸道刺激
H302+H332

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

UN Number 1993

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 794 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Liver - change in gall bladder structure or function
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   NTIS** National Technical Inf

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intramuscular
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JSICAZ Journal of Scientific and Industrial Research, Section C: Biological
   Sciences.  (New Delhi, India)  V.14-21, 1955-62.  For publisher information,
   see IJEBA6.  Volume(issue)/page/year: 21,342,1962

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 272 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
   Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium)  V.4-   
   1898-  Volume(issue)/page/year: 135,330,1962

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUT

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2200 mg/kg
TOXIC EFFECTS :
   Behavioral - general anesthetic
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 25,199,1943

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human Leukocyte
DOSE/DURATION           : 100 umol/L
REFERENCE :
   DBTEAD Diabete.  (Le Raincy, France)  V.1-22, 1953-74.  Discontinued.
   Volume(issue)/page/year: 19,215,1971

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Mammal - species unspecified Lymphocyte
DOSE/DURATION           : 150 mmol/L
REFERENCE :
   PNASA6 Proceedings of the National Academy of Sciences of the United States
   of America.  (National Academy of Sciences, Printing & Pub. Office, 2101
   Constitution Ave., Washington, DC 20418) V.1-    1915-
   Volume(issue)/page/year: 48,686,1962

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - gerbil
DOSE                    : 315 mg/kg
SEX/DURATION            : male 21 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
   Reproductive - Paternal Effects - prostate, seminal vesicle, Cowper's gland,
   accessory glands
REFERENCE :
   IJEBA6 Indian Journal of Experimental Biology.  (Publications & Information
   Directorate, CSIR, Hillside Rd., New Delhi 110 012, India)  V.1-    1963-
   Volume(issue)/page/year: 17,1305,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 315 mg/kg
SEX/DURATION            : male 21 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
   Reproductive - Paternal Effects - prostate, seminal vesicle, Cowper's gland,
   accessory glands
REFERENCE :
   IJEBA6 Indian Journal of Experimental Biology.  (Publications & Information
   Directorate, CSIR, Hillside Rd., New Delhi 110 012, India)  V.1-    1963-
   Volume(issue)/page/year: 17,1305,1979

其他信息

方法一:工业生产方法主要为苯酚加氢法和环己烷氧化法。1.苯酚加氢法苯酚蒸气和氢气在镍催化剂存在下，在110-185℃、压力1.078-1.471MPa，在管式反应器中进行加氢反应制得环己醇蒸气产品，经换热、冷凝、分离除氢后再精馏得成品。2.环己烷氧化法苯蒸气在镍催化剂存在下，于120-180℃进行加氢反应得环己烷，环己烷氧化制造环己醇根据不同催化剂分为以下三种方法：（1）钴盐催化法　以环烷酸钴，硬脂酸钴或辛酸钴为催化剂。（2）硼酸催化法以硼酸或偏硼酸为催化剂，在空气氧化过程中，硼酸与环己基过氧化氢生成过硼酸环己醇酯，然后再变成硼酸环己醇酯，或者与生成的环己醇结合生成硼酸环己醇酯和偏硼酸环己醇酯。然后水解，油相经提纯即得成品。（3）无催化剂氧化法以环己烷为原料，在压力1.47-1.96MPa，温度170-200℃下，用氧含量为10%-15%的空气氧化得环己基过氧化氢，再经浓缩后，于70-160℃催化分解，即得环己醇和环己酮。
急性毒性:口服- 大鼠 LD50: 2060 毫克/ 公斤; 腹注- 小鼠 LD50: 1352 毫克/ 公斤
下游产品:环己酮 --> 己二酸 --> 1,6-己内酰胺 --> 环己胺 --> 环己烯 --> (R)-3-羟基吡咯烷盐酸盐 --> 氯代环己烷 --> 溴代环己烷 --> 环己甲酸 --> 二环己基二硫化物 --> 环己硫醇 --> 过氧化二碳酸二环己酯[工业纯] --> 苯次磺
毒性分级:中毒
环己醇价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 30046428 环己醇 500ml 39.8元 2011/08/23 40011062 环己醇 2ml 49元 2010/06/21 14768002
刺激数据:眼- 兔子 2 毫克重度; 皮肤- 兔子 14.6 毫克/ 24小时轻度
Acros Organics:环己醇 Cyclohexanol, 98%(108-93-0)
图谱信息:环己醇(108-93-0)核磁图( 13 CNMR) 环己醇(108-93-0)质谱(MS) 环己醇(108-93-0)红外图谱(IR1) 环己醇(108-93-0)红外图谱(IR2) 环己醇(108-93-0)核磁图( 1 HN
Alfa Aesar:环己醇,99% Cyclohexanol, 99%(108-93-0)
爆炸物危险特性:与空气混合可爆
可燃性危险特性:遇明火、高温、强氧化剂可燃；燃烧排放刺激烟雾
MOL 文件:108-93-0.mol
类别:易燃液体
{C
用途三:比色法测定钼和铼，以苯肼测定铝。以8-羰基喹啉或以碘化物测定铋时作溶剂，以提取带色物质。橡胶、树脂和硝化棉溶剂。杀虫剂。
敏感性:Hygroscopic
上游原料:苯 --> 过氧化氢 --> 氢 --> 环己烷 --> 环己酮 --> 辛酸 --> 环烷酸钴 --> 偏硼酸 --> 硬脂酸钴
用途一:用于环己醇脱氢过程
储运特性:库房通风低温干燥
有似樟脑气味，有吸湿性。能与醇、乙酸乙酯、亚麻子油和芳香烃类混溶。20℃时水中溶解度为3.6g/100g,20℃时水在环己醇中的溶解度为11g/100g。低毒，半数致死量（大鼠，经口）2060mg/kg。有刺激性。
用途二:重要的化工原料，主要用于生产己二酸、己二胺、环己酮、己内酰胺，也可用作肥皂的稳定剂，制造消毒药皂和去垢乳剂，用作橡胶、树脂、硝基纤维、金属皂、油类、酯类、醚类的溶剂，涂料的掺合剂，皮革的脱脂剂、脱膜剂、干洗剂、擦亮剂。环己醇也是纤维整理剂、杀虫剂、增塑剂的原料，环己醇与光气反应得到氯甲酸环己酯，是引发剂过氧化二碳酸二环己酯的中间体。
Sigma Aldrich:108-93-0(sigmaaldrich)
职业标准:TLV-TWA 50 PPM (200 毫克/ 立方米); STEL 75 PPM (300 毫克/ 立方米)
{Chemicalbook

Cyclohexanol 环己醇

CAS 108-93-0 MFCD00003855

化学结构图

化学属性

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化学结构图

化学属性

别名和识别编码

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相关文献及参考

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相关产品推荐

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