1,1,3,3-Tetraethoxypropane 1,1,3,3-四乙氧基丙烷

CAS 122-31-6 MFCD00009240

化学结构图

122-31-6
SMILES: CCOC(CC(OCC)OCC)OCC

化学属性

Mol. FormulaC11H24O4
Mol. Weight220
Density0.919
Refractive index1.4100 to 1.4120
Boiling Point220
Flash Point42°C
Melting Point-90
Solubility不溶于水,溶于乙醇和醚。

别名和识别编码

Chemical Name1,1,3,3-Tetraethoxypropane
Synonym 1,1,3,3-Tetraethoxypropane Malonaldehyde bis(diethyl acetal) TEP 丙二醛二乙缩醛 丙二醛乙缩醛;丙二醛缩双(二乙醇)
CAS Number122-31-6
EC Number204-533-1
Beilstein Registry Number1209619
MDL NumberMFCD00009240
PubChem Substance ID67147
Chemical Name Translation1,1,3,3-四乙氧基丙烷
Reaxys-RN1209619
Wiswesser Line Notation2OYO2&1YO2&O2
LabNetwork Molecule IDLN00008633
InChIInChI=1S/C11H24O4/c1-5-12-10(13-6-2)9-11(14-7-3)15-8-4/h10-11H,5-9H2,1-4H3
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分类

  • {SNA} Acetals/Ketals/Ortho Esters, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 用作医药和染料中间体,也可以坐为农产品保鲜剂的中间体。

相关文献及参考

  • Beilstein:1(3)3095
  • Short: EINECS
  • Short: III/38B

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P303+P361+P353
  • P370+P378
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H226 Flammable liquid and vapour 易燃液体和蒸气
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSON8750000
Hazard Codes Xn
UN Number 1993 3271
Packing GroupIII
Storage condition 储存温度 2-8°C 2-8°C
Hazard Class3
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1610 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle contraction or spasticity
   Lungs, Thorax, or Respiration - dyspnea
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   7,826,1965

TYPE OF TEST            : Morphological transformation
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 10080 mg/kg/6W
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 9,387,1988

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 4 umol/plate
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   40,276,1980

其他信息

  • 1,1,3,3-四乙氧基丙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 39016880 1,1,3,3-四乙氧基丙烷(2-8℃) 50ml 330元 2011/08/23 39016881 1,1,3,3-四乙氧基丙烷(2-8℃) 100ml 600元 2011/08/23 TT009302 1.1.3.3-四乙氧基丙烷 95% 25ml 235元
  • MSDS 信息:1,1,3,3-Tetraethoxypropane(122-31-6).msds
  • 用途二:用作医药和染料中间体,也可以坐为农产品保鲜剂的中间体。
  • 检测方法:GC
  • 不溶于水,溶于乙醇和醚。
  • 外观:常温下为无色略有刺激味的易燃透明液体。
  • MOL 文件:122-31-6.mol
  • 联合国UN编码:UN1993
  • 用途一:用作医药和染料中间体,也可以作为农产品保鲜剂的中间体
  • 海关编码:29110000
  • 图谱信息:1,1,3,3-四乙氧基丙烷(122-31-6)质谱(MS)
  • TCI Shanghai:丙二醛缩双(二乙醇) 1,1,3,3-Tetraethoxypropane,>;95.0%(GC)(122-31-6)
  • Acros Organics:1,1,3,3-四乙氧基丙烷 Malonaldehyde bis(diethyl acetal), 97%(122-31-6)
  • 下游产品:高哌嗪 --> 异恶唑 --> N4-苯甲酰基胞嘧啶 --> 4-(1H吡唑-1-基)苯磺酰氯
  • Sigma Aldrich:122-31-6(sigmaaldrich)

系列性分类


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