(+)-Diisopropyl L-tartrate L-(+)-酒石酸二异丙酯

CAS 2217-15-4 MFCD00064450

化学结构图

2217-15-4
SMILES: CC(C)OC(=O)[C@H](O)[C@@H](O)C(=O)OC(C)C

化学属性

Mol. FormulaC10H18O6
Mol. Weight234
Density1.140
Boiling Point275
Refractive index1.4380 to 1.4400
Flash Point110°C(lit.)
TSCANo
Stability易吸潮
pH:A

别名和识别编码

Chemical Name(+)-Diisopropyl L-tartrate
Synonym (+)-DIPT Diisopropyl L-(+)-tartrate (+)-diisopropyl L-tartrate Lg-threaric acid diisopropyl ester DIISOPROPYL L-TARTRATE 2,3-dihydroxy- (R-(R*,R*))-butanedioic acid, bis(1-methylethyl) ester L(+)-Weinsäurediisopropylester Butanedioic acid, 2,3-dihydroxy- (2R,3R)-, bis(1-methylethyl) ester (2R,3R)-(+)-diisopropyl tartrate (+)-L-TARTARIC ACID DIISOPROPYL ESTER d(+)-tartaric acid diisopropyl ester 2,3-dihydroxy- R-R*,R*-butanedioic acid, bis1-methylethyl ester (2R,3R)-(+)-Diisopropyltartrat Diisopropyl L-(+)-tartarate L-Tartaric acid diisopropyl ester {uni_hambur L(+)-DIISOPROPYL TARTRATE L-(+)-Diisopropyl tartrate DIISOPROPYL L-(+)-TARTRATE DIISOPROPYL (2R,3R)-2,3-DIHYDROXYSUCCINATE Diisopropyl (2R,3R)-tartrate Diisopropyl (+)-L-tartrate Tartaricacid,diisopropyle (+)-二异丙酯-L-(+)-酒石酸 Lg-threaricaciddiisopropylester 2,3-dihydroxy-succinicaciddiisopropylester {C Weinsäuredipropylester L-(+)-Tartaric acid diisopropyl ester L-(+)-TARTARIC ACID DIISOPROPYL ESTER Butanedioic acid, 2,3-dihydroxy-[R-(R*,R*)]-, bis(1-methyle tartaricaciddiisopropylester 二异丙基酒石酸 Lg-tartaric acid diisopropyl ester dii (R,R)-2,3-dihydroxy-succinicaciddiisopropylester L-DI Lg-tartaricaciddiisopropylester L-(+)-酒石酸二异丙酯 Butanedioic acid, 2,3-dihydroxy- [R-(R Diisopropyl R,R-tartrate (R,R)-2,3-dihydroxy-succinic acid diisopropyl ester L-酒石酸二
CAS Number2217-15-4
EC Number218-709-0
Beilstein Registry Number1727863
MDL NumberMFCD00064450
PubChem Substance ID6453580
Chemical Name TranslationL-(+)-酒石酸二异丙酯
Reaxys-RN1727863
InChIKeyXEBCWEDRGPSHQH-HTQZYQBOSA-N
Wiswesser Line Notation1Y1&OVYQYQVOY1&1
LabNetwork Molecule IDLN00201300
InChIInChI=1S/C10H18O6/c1-5(2)15-9(13)7(11)8(12)10(14)16-6(3)4/h5-8,11-12H,1-4H3/t7-,8-/m1/s1
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分类

  • {uni_hamburg} no charge; ester; alcohol; chiral; 1fragment
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Epoxidation, Esters, Organic Building Blocks

产品应用

  • 用于有机合成。制备手性化合物。通过对映选择环氧化作用,用作外消旋烯丙基醇类的动力拆分。

相关文献及参考

  • Chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols; see tert-Butyl­ hydroperoxide, A13926.
  • Beilstein:3(2)331
  • Short: EINECS
  • Short: IV/1b
  • Short: IV/18B
  • Short: IV/20B

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
RTECSWW8100000
Personal Protective Equipment Eyeshields, Gloves
Storage condition 易吸潮,密封保存。
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 93,26,1948

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >10 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 93,26,1948

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 6300 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 93,26,1948

其他信息

  • 图谱信息:L-(+)-酒石酸二异丙酯(2217-15-4)Raman光谱 L-(+)-酒石酸二异丙酯(2217-15-4)核磁图( 13 CNMR) L-(+)-酒石酸二异丙酯(2217-15-4)红外图谱(IR1) L-(+)-酒石酸二异丙酯(2217-15-4)质谱(MS)
  • 海关编码:29181300
  • 比旋光度:17.25 ° (neat)
  • MOL 文件:2217-15-4.mol
  • TCI Shanghai:L-(+)-酒石酸二异丙酯 Diisopropyl L-(+)-Tartrate,>;98.0%(GC)(2217-15-4)
  • L-(+)-酒石酸二异丙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0621 L-(+)-酒石酸二异丙酯 Diisopropyl L-(+)-Tartrate 25G 279元 2014/06/02 T0621 L-(+)-酒石酸二异丙酯 Diisopropyl L-(+)-Tartrate 500G 2370元 2010/06/21 212030050 L-(+)-酒石酸二异丙酯 (+)-Diisopropyl L-tartrate 99% 5 GR 108元
  • Acros Organics:L-酒石酸二异丙酯 (+)-Diisopropyl L-tartrate, 99%(2217-15-4)
  • 敏感性:Hygroscopic
  • MSDS 信息:(+)-Diisopropyl L-tartrate(2217-15-4).msds
  • Sigma Aldrich:2217-15-4(sigmaaldrich)
  • 用途一:用于有机合成。制备手性化合物。通过对映选择环氧化作用,用作外消旋烯丙基醇类的动力拆分。
  • Alfa Aesar:L-(+)-酒石酸二异丙酯,98+% (+)-Diisopropyl L-tartrate, 98+%(2217-15-4)

系列性分类


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