Methyl Nitroacetate 硝基乙酸甲酯

CAS 2483-57-0 MFCD00075480

化学结构图

2483-57-0
SMILES: COC(=O)C[N+](=O)[O-]

化学属性

Mol. FormulaC3H5NO4
Mol. Weight119.08
Density1.294 g/mL at 25 °C(lit.)
Refractive index1.4230 to 1.4270
Boiling Point195-198 °C at 760 mmHg
Flash Point95°C(lit.)
TSCANo

别名和识别编码

Chemical NameMethyl Nitroacetate
CAS Number2483-57-0
EC Number219-622-0
Beilstein Registry Number2(4)537
MDL NumberMFCD00075480
PubChem Substance ID17206
Reaxys-RN1758670
Synonym Methyl 2-nitroacetate {LY} Methyl 2-nitroacetate {} {LY} Methyl 2-nitroacetate {} {} {LY} Methyl 2-nitroacetate {} {} {} {LY} Methyl 2-nitroacetate {} {} {} {} {LY} Methyl 2-nitroacetate {} {} {} {} {} {LY} Methyl 2-nitroacetate {} {} {} {} {} {} {LY} Methyl 2-nitroacetate {} {} {} {} {} {} {} {LY} Methyl 2-nitroacetate {} {} {} {} {} {} {} {} {LY} Methyl 2-nitroacetate {} {} {} {} {} {} {} {} {} {LY} Methyl 2-nitroacetate {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-nitroacetate {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-nitroacetate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-nitroacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-nitroacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-nitroacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-nitroacetate {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation硝基乙酸甲酯
InChIKeyALBSWLMUHHZLLR-UHFFFAOYSA-N
LabNetwork Molecule IDLN00202171
InChIInChI=1S/C3H5NO4/c1-8-3(5)2-4(6)7/h2H2,1H3
Canonical SMILESO=C(OC)C[N+]([O-])=O
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分类

  • Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • {SNA} Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

相关文献及参考

  • Beil. 2 ,IV,537
  • FT-NMR 1 (1), 1081:A / RegBook 1 (1), 777:F / Structure Index 1 , 121:B:2

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H303 May be harmfully swallowed 吞食可能有害
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi
RTECSAJ1093000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
Signal word Warning {} {} {} {} {TCI}
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Storage condition 2-8°C {LY} 2-8°C Light Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {}
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       :

TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : >651 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 24(7),49,1980

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3770 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - acute pulmonary edema
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 24(7),49,1980

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3940 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - acute pulmonary edema
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 24(7),49,1980

TYPE OF TEST

其他信息

  • Sigma Aldrich:2483-57-0(sigmaaldrich)
  • Alfa Aesar:硝基乙酸甲酯,98% Methyl nitroacetate, 98%(2483-57-0)
  • TCI Shanghai:硝基乙酸甲酯 Methyl Nitroacetate,>;95.0%(GC)(2483-57-0)
  • F:8
  • Acros Organics:硝基乙酸甲酯 Methyl nitroacetate, 98%(2483-57-0)
  • 硝基乙酸甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0656 硝基乙酸甲酯 Methyl Nitroacetate 5G 1340元 2014/06/02 N0656 硝基乙酸甲酯 Methyl Nitroacetate 25G 4620元 2010/06/21 356120010 硝基乙酸甲酯 Methyl nitroacetate 98% 1 GR 1084元
  • MOL 文件:2483-57-0.mol
  • 敏感性:Light Sensitive

系列性分类


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