(+)-10-Camphorsulfonic acid (+)-10-樟脑磺酸

CAS 3144-16-9 MFCD00064157

化学结构图

3144-16-9
SMILES: CC1(C)C2CCC1(CS(=O)(=O)O)C(=O)C2

化学属性

Mol. FormulaC10H16O4S
Mol. Weight232.30
Melting Point196-200°C
TSCAYes
Density1.331
Stability易吸潮
Appearance D(+)-10-樟脑磺酸(3144-16-9)为白色结晶体或结晶性粉末,不溶于醚,微溶于冰醋酸、乙酸乙酯,在潮湿的空气中易潮解。熔点195-200℃
SolubilitySOLUBLE
Refractive index21.5 ° (C=5, H2O)
Boiling Point344.46 °C at 760 mmHg

别名和识别编码

Chemical Name(+)-10-Camphorsulfonic acid
Synonym (+)-D-Camphor-10-sulfonic acid {LY} (+)-D-Camphor-10-sulfonic acid {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulf
CAS Number3144-16-9
PubChem Substance ID65617
EC Number221-554-1
Beilstein Registry Number2809675
MDL NumberMFCD00064157
Merck Number1734
Chemical Name Translation(+)-10-樟脑磺酸
Reaxys-RN2809675
LabNetwork Molecule IDLN00190061
InChIInChI=1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m1/s1
Canonical SMILESCC1(C)[C@@H]2CC[C@]1(CS(=O)(O)=O)C(C2)=O
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分类

  • {SNA} Analytical Reagents,
  • {SNA} Ana
  • {SA} Analytical Reagents, Analytical/Chromatography, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Derivatization Reagents, Derivatization Reagents HPLC, Organic Building Blocks, Sulfonic/Sulfinic Acids, UV-VIS
  • Analytical Reagents, Analytical/Chromatography, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Derivatization Reagents, Derivatization Reagents HPLC, Organic Building Blocks, Sulfonic/Sulfinic Acids, UV-VIS

产品应用

  • 可作为拆分剂,以及二肽偶联的催化剂。

相关文献及参考

  • Merck: 14,1734
  • Resolving agent for optically-active bases. For an improved resolution technique, using two immiscible solvents and half equivalent of resolving agent, see: Tetrahedron, 41, 2465 (1985). The procedure is claimed to lead to faster resolutions with higher optical purities than conventional methods.
  • Merck: 14,1734 Beilstein:11,314

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 8
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSED1550000
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Packing GroupII
UN Number 3261
Risk Statements
  • R34 Causes burns 会导致灼伤
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class8
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2502 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PHARAT Pharmazie.  (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18,
   Berlin DDR-1020, Ger. Dem. Rep.)  V.1-    1946-  Volume(issue)/page/year:
   1,150,1946

其他信息

  • 海关编码:29147090
  • 比旋光度:22 ° (589nm, c=20, H2O 25 °C)
  • MSDS 信息:1S-(+)-Camphor-10-sulfonic acid(3144-16-9).msds
  • 用途一:用于医药中间体或异构体产品拆分
  • F:3-10
  • D(+)-10-樟脑磺酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30035224 D-樟脑-10-磺酸 25g 94元 2011/04/16 C0015 (+)-10-樟脑磺酸 (+)-10-Camphorsulfonic Acid 500G 1550元 2011/04/16 C0015 (+)-10-樟脑磺酸 (+)-10-Camphorsulfonic Acid 25G 268元
  • Acros Organics:D(+)-10-樟脑磺酸 D(+)-10-Camphorsulfonic acid, 99%(3144-16-9)
  • 用途二:用于制药工业
  • 图谱信息:D(+)-10-樟脑磺酸(3144-16-9)质谱(MS) D(+)-10-樟脑磺酸(3144-16-9)红外图谱(IR2) D(+)-10-樟脑磺酸(3144-16-9)红外图谱(IR1)
  • Sigma Aldrich:3144-16-9(sigmaaldrich)
  • Alfa Aesar:<2%(3144-16-9)" href="http://www.alfa.com/zh/GP100w.pgm?DSSTK=A16179&CAS;=3144-16-9">(1S)-(+)-樟脑-10-磺酸,98+% (1S)-(+)-Camphor-10-sulfonic acid, 98+%(dry wt.), water <2%(3144-16-9)
  • 检测方法:T
  • 敏感性:Hygroscopic
  • 下游产品:(S)-(+)-3-喹宁醇 --> 盐酸左旋咪唑 --> 7-(3,5,6-三甲基-1,4-苯醌-2-基)-7-苯基庚酸
  • 不溶于醚,微溶于冰醋酸、乙酸乙酯,在潮湿的空气中易潮解。
  • MOL 文件:3144-16-9.mol
  • TCI Shanghai:(+)-10-樟脑磺酸 (+)-10-Camphorsulfonic Acid,>;98.0%(T)(3144-16-9)
  • 用途三:有机合成中间体,拆分剂。

系列性分类


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