2-Acetyl-6-methoxynaphthalene 6-甲氧基-2-乙酰萘

CAS 3900-45-6 MFCD00021643

化学结构图

3900-45-6
SMILES: COc1ccc2cc(C(C)=O)ccc2c1

化学属性

Mol. FormulaC13H12O2
Mol. Weight200.23
Melting Point107-109°C
TSCANo
Boiling Point343.4°C at 760 mmHg
Density1.118
Flash Point155-160°C/0.4mm
Appearance 白色结晶体。熔点106.5-108℃。

别名和识别编码

Chemical Name2-Acetyl-6-methoxynaphthalene
CAS Number3900-45-6
Alfabeta NameACETYLMETHOXYNAPHTHALENE 26---
MDL NumberMFCD00021643
Synonym 6'-Methoxy-2'-acetonaphthone {LY} 6'-Methoxy-2'-acetonaphthone {} {LY} 6'-Methoxy-2'-acetonaphthone {} {} {LY} 6'-Methoxy-2'-acetonaphthone {} {} {} {LY} 6'-Methoxy-2'-acetonaphthone {} {} {} {} {LY} 6'-Methoxy-2'-acetonaphthone {} {} {} {} {} {LY} 6'-Methoxy-2'-acetonaphthone {} {} {} {} {} {} {LY} 6'-Methoxy-2'-acetonaphthone {} {} {} {} {} {} {} {LY} 6'-Methoxy-2'-acetonaphthone {} {} {} {} {} {} {} {} {LY} 6'-Methoxy-2'-acetonaphthone {} {} {} {} {} {} {} {} {} {LY} 6'-Methoxy-2'-acetonaphthone {} {} {} {} {} {} {} {} {} {} {LY} 6'-Methoxy-2'-acetonaphthone {} {} {} {} {} {} {} {} {} {} {} {LY} 6'-Methoxy-2'-acetonaphthone {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6'-Methoxy-2'-acetonaphthone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6'-Methoxy-2'-acetonaphthone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6'-Methoxy-2'-acetonaphthone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID77506
EC Number223-453-8
Reaxys-RN1871098
Beilstein Registry Number8(4)1178
Chemical Name Translation6-甲氧基-2-乙酰萘
LabNetwork Molecule IDLN00173697
InChIInChI=1S/C13H12O2/c1-9(14)10-3-4-12-8-13(15-2)6-5-11(12)7-10/h3-8H,1-2H3
Canonical SMILESCC(C1=CC=C2C=C(OC)C=CC2=C1)=O
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分类

  • Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
  • {SNA} Analytical Standards, Analytical/Chromatography, Chromatography, EP Standards, EP Standards N - O, Pharmaceutical Standards, Pharmacopeia Standards
  • {SNA} Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks

产品应用

  • 非甾体抗炎痛新药萘普生(Naproxen)及萘普酮(Nabumetone)的化学合成关键中间体, 医药萘普生的中间体。

相关文献及参考

  • Beilstein:8(4)1178
  • Boynton, C., et al.: J. Clin. Pharmacol., 28, 512

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

  • Acros Organics:2-乙酰基-6-甲氧基萘 2-Acetyl-6-methoxynaphthalene, 98%(3900-45-6)
  • 下游产品:萘普生
  • Alfa Aesar:2-乙酰基-6-甲氧基萘,98% 2-Acetyl-6-methoxynaphthalene, 98%(3900-45-6)
  • 用途二:医药萘普生的中间体。
  • 上游原料:乙醇 --> 甲醇 --> 硫酸 --> 三氯化铝 --> 乙酰氯 --> 2-羟基萘 --> 硝基苯 --> 2-萘甲醚
  • Sigma Aldrich:3900-45-6(sigmaaldrich)
  • MOL 文件:3900-45-6.mol
  • 6-甲氧基-2-乙酰萘价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A2030 2-乙酰基-6-甲氧基萘 2-Acetyl-6-methoxynaphthalene 500G 5410元 2014/06/02 A2030 2-乙酰基-6-甲氧基萘 2-Acetyl-6-methoxynaphthalene 25G 624元 2010/06/21 134780100 6-甲氧基-2-乙酰萘 2-Acetyl-6-methoxynaphthalene 98% 10 GR 1354元
  • 方法一:2-甲氧基萘在三氯化铝存在下用乙酐进行乙酰化反应可制得成品。
  • Hazard Note:Irritant
  • TCI Shanghai:6-甲氧基-2-乙酰萘 2-Acetyl-6-methoxynaphthalene,>;98.0%(GC)(3900-45-6)
  • 用途三:非甾体抗炎痛新药萘普生(Naproxen)及萘普酮(Nabumetone)的化学合成关键中间体, 医药萘普生的中间体。
  • 用途一:用于合成非甾体抗炎镇痛新药萘普生及萘普酮的关键中间体
  • MSDS 信息:1-(6-Methoxy-2-naphthyl)ethan-1-one(3900-45-6).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C13 to C14 - Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones 酮
  6. C11 to C12

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