2-Bromoethyl ethyl ether 2-溴乙基乙基醚

CAS 592-55-2 MFCD00000237

化学结构图

592-55-2
SMILES: CCOCCBr

化学属性

Mol. FormulaBrCH2CH2OC2H5
Mol. Weight153
Refractive index1.4430 to 1.4470
Boiling Point149-150
Density1.357
Flash Point21°C(lit.)
TSCAYes
Solubility略溶于水

别名和识别编码

Chemical Name2-Bromoethyl ethyl ether
CAS Number592-55-2
PubChem Substance ID61141
EC Number209-763-6
MDL NumberMFCD00000237
Beilstein Registry Number1,338
Reaxys-RN1731362
Synonym 2-Ethoxyethyl bromide 1-溴-2-乙氧基乙烷 2-Bromo-2-ethoxyethane Ethane, 1-bromo-2-ethoxy- 5-Bromo-3-oxapentane 1-bromo-2-ethoxy-ethan Ethyl 2-bromoethyl ether 1-bromo-2-ethoxy-ethane 2-BROMOETHYL ETHYL ETHER 2-Bromoethyl ethyl ether ,96% TIMTEC-BB SBB008332 2-Bromethyl-ethylether 2-溴乙基乙醚 1-Bromo-2-ethoxyethane 2-Bromoethyl ethyl ether 1-Bromo-2-ethoxyethylene 2-BROMODIETHYL ETHER 2-Bromethylethylether 2-Bromoethyl Ethyl Ether, Pract. 2-乙氧基乙基溴 2-Ethoxyethyl Bromide, Pract. 2-溴乙基乙基醚; 2-溴乙基乙醚 2-BROMOETHYL ETHYL ETHER, TECH., 90% 1-Bromo-3-oxapentane 1-Brom-2-ethoxyethan 1-Ethoxy-2-bromoethane 2-溴乙基醚 Ethyl(2-bromoethyl) ether 2-ETHOXYETHYL BROMIDE BROMOETHYL ETHYL ETHER ethyl-(2-bromo-ethyl)-ether 2-Bromoethoxyethane 2-溴乙基乙基醚 Ether, 2-bromoethyl ethyl 2-Ethoxyethylbromid
Chemical Name Translation2-溴乙基乙基醚
InChIKeyMMYKTRPLXXWLBC-UHFFFAOYSA-N
LabNetwork Molecule IDLN00007953
InChIInChI=1S/C4H9BrO/c1-2-6-4-3-5/h2-4H2,1H3
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分类

  • {SNA} Building Blocks, C2 to C7, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds
  • {uni_hamburg} no charge; ether; 1fragment
  • Building Blocks, C2 to C8, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • Short: EINECS
  • Short: IV/16
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305 IF IN EYES: 如果进入眼睛
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 2340 UN 2340 3/PG 2
Storage condition Moisture Sensitive <;0 <0°C Freezer
Packing GroupII
Hazard Class3
RTECSKN3950000
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • 上游原料:无水氯化钙 --> 三溴化磷 --> 乙二醇乙醚
  • 方法一:将三溴化磷滴加到2-乙氧基乙醇中，加热回流。然后蒸馏出150℃以下馏出物，水洗，干燥得成品，产率约60%。
  • 检测方法:GC,NMR,MS
  • 海关编码:29091900
  • 2-溴乙基乙基醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0595 2-溴乙基乙基醚 2-Bromoethyl Ethyl Ether 25G 605元 2014/06/02 B0595 2-溴乙基乙基醚 2-Bromoethyl Ethyl Ether 500G 4600元 2010/06/21 367401000 2-溴乙基乙基醚 2-Bromoethyl ethyl ether 90% 100 GR 1849元
  • 用途一:有机合成中间体。
  • Acros Organics:2-溴乙基乙醚 2-Bromoethyl ethyl ether, 90%(592-55-2)
  • TCI Shanghai:2-溴乙基乙基醚 2-Bromoethyl Ethyl Ether,>;95.0%(GC)(592-55-2)
  • Sigma Aldrich:592-55-2(sigmaaldrich)
  • MOL 文件:592-55-2.mol
  • 外观性质:无色液体。
  • 图谱信息:2-溴乙基乙基醚(592-55-2)红外图谱(IR1) 2-溴乙基乙基醚(592-55-2)核磁图( 13 CNMR) 2-溴乙基乙基醚(592-55-2)核磁图( 1 HNMR) 2-溴乙基乙基醚(592-55-2)质谱(MS)
  • MSDS 信息:2-溴乙基乙醚(592-55-2).msds
  • Alfa Aesar:2-溴乙基乙基醚,95% 2-Bromoethyl ethyl ether, 95%(592-55-2)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  6. C2 to C8 - Ethers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides

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