Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate 氟磺酰基二氟乙酸甲酯

CAS 680-15-9 MFCD00144316

化学结构图

680-15-9
SMILES: COC(=O)C(F)(F)S(=O)(=O)F

化学属性

Mol. FormulaC3H3F3O4S
Mol. Weight192.11
Boiling Point117-118 °C at 760 mmHg
Density1.51
Refractive index1.3500 to 1.3520
Flash Point44.5±27.3 °C
TSCANo
Stability对湿度敏感
Danger-Level乙类

别名和识别编码

Chemical NameMethyl 2,2-difluoro-2-(fluorosulfonyl)acetate
CAS Number680-15-9
Alfabeta NameMETHYLFLUOROSULFONYLDIFLUOROACETATE 2()-
MDL NumberMFCD00144316
Beilstein Registry Number1812896
EC Number250-023-7
PubChem Substance ID87570085
Synonym Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate {LY} Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate {} {LY} Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate {} {} {LY} Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate {} {} {} {LY} Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate {} {} {} {} {LY} Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate {} {} {} {} {} {} {LY} Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate {} {} {} {} {} {} {} {LY} Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate {} {} {} {} {} {} {} {} {LY} Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate {} {} {} {} {} {} {} {} {} {LY} Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2,2-difluoro-2-(fluorosulf
Chemical Name Translation氟磺酰基二氟乙酸甲酯
Reaxys-RN1812896
LabNetwork Molecule IDLN00009015
Canonical SMILESO=C(OC)C(F)(F)S(=O)(F)=O
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分类

  • {SNA} Alkyl Fluorinated Building Blocks, Building Blocks, Chemical Synthesis, Difluoromethylation, Fluorinated Building Blocks, Fluorination Reagents, Mono-Functionalized Sulfonyl Fluorides, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks, SuFEx: The Next Click Reaction, Sulfonyl Halides, Sulfur Compounds, Synthetic Reagents
  • {SNA} Alkyl Fluorinated B
  • {SNA} Alkyl Fluorinated Building Blocks, Building Blocks, Chemical Synthesis, Difluoromethylation, Fluorinated Building Blocks, Fluorination Reagents, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks,

产品应用

  • 用于卤代烷的三氟甲基化

相关文献及参考

  • Beilstein:2(4)1856

安全信息

Warnings IRRITANT
UN Number 2920
Risk Statements
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Signal word Danger
GHS Symbol
WGK Germany3
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C C,Xi
Packing GroupII
Hazard Class8/3
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 存储注意事项:湿度敏感
  • 氟磺酰基二氟乙酸甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 F0311 氟磺酰二氟乙酸甲酯 Methyl Fluorosulfonyldifluoroacetate 5G 374元 2014/06/02 F0311 氟磺酰二氟乙酸甲酯 Methyl Fluorosulfonyldifluoroacetate 25G 1150元
  • Sigma Aldrich:680-15-9(sigmaaldrich)
  • Hazard Note:Irritant
  • F:10-21
  • MOL 文件:680-15-9.mol
  • 图谱信息:氟磺酰基二氟乙酸甲酯(680-15-9)红外图谱(IR1) 氟磺酰基二氟乙酸甲酯(680-15-9)核磁图( 1 HNMR) 氟磺酰基二氟乙酸甲酯(680-15-9)核磁图( 13 CNMR) 氟磺酰基二氟乙酸甲酯(680-15-9)质谱(MS)
  • 检测方法:GC,NMR
  • TCI Shanghai:氟磺酰二氟乙酸甲酯 Methyl Fluorosulfonyldifluoroacetate,>;97.0%(GC)(680-15-9)

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Titration - Analytical Reagents
  4. Complexometric Titration Reagents (EDTA Titration) - Titration
  5. Complexometric Solutions (IDRANAL™) - Complexometric Titration Reagents (EDTA Titration)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonyl Halides - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonyl Halides - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TA - TE - T
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorous Chemistry 氟化学
  1. Functional Group 官能团索引
  2. orthocarboxylic acid derivative
  1. sulfonyl halide

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