Dimethyldiselenide 二甲基二硒醚

CAS 7101-31-7 MFCD00008254

化学结构图

7101-31-7
SMILES: C[Se][Se]C

化学属性

Mol. Formula(CH3)2Se2
Mol. Weight187.99
Refractive indexn20/D 1.6388(lit.)
Boiling Point155-157 °C(lit.)
Density1.987 g/mL at 25 °C(lit.)
Flash Point60°C(lit.)
TSCANo
Melting Point-82.2 °C

别名和识别编码

Chemical NameDimethyldiselenide
Synonym Methyl diselenide dimethyl-diselane Methyldiselanylmethane Dimethyldiselenide 二甲基二硒醚 1,2-Dimethyldiselane dimethyl diselenide Dimethyldiselenid dimethyldiselenium 二甲基联硒 甲基二硒 DIMETHYL DISELENIDE 二甲基二硒 联[二]硒二甲酯 Diselenide, dimethyl METHYL DISELENIDE Dimethyl perselenide (CH3Se)2 Dimethyl perdiselenide dimethyl-diselenide Dimethyldiselenium
MDL NumberMFCD00008254
CAS Number7101-31-7
PubChem Substance ID23496
EC Number230-410-7
Reaxys-RN1696897
Beilstein Registry Number1(4)1288
Chemical Name Translation二甲基二硒醚
InChIKeyVLXBWPOEOIIREY-UHFFFAOYSA-N
LabNetwork Molecule IDLN01744067
InChIInChI=1S/C2H6Se2/c1-3-4-2/h1-2H3
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Selenium Compounds
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
  • Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25B Year: 1999 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-63645-5 ISBN: 978-3-540-63645-8 Internet Resource: DOI:10.1007/b68834 RefComment: IX, 512 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H301+H331
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H331 Toxic if inhaled 吸入中毒
  • H301 Toxic if swallowed 吞食有毒
  • H311 Toxic in contact with skin 皮肤接触中毒
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P304+P340+P310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P301+P310
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P403+P233
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+P361+P353
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P302+P352+P310+P361+P364
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P241+P242+P243
  • P301+P310+P330
  • P405 Store locked up. 上锁保管。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
Signal word Danger
Packing GroupII
UN Number UN2929 UN 2929 6.1/PG 2 3440 2929
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
  • R50/53
  • R33 Danger of cumulative effects 有累积作用的危险
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S20/21 When using do not eat, drink or smoke 使用时,不得进食,饮水或吸烟;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Storage condition Air & Moisture Sensitive 0-6°C
Hazard Codes T T,N T;N
Hazard Class6.1

其他信息

  • Sigma Aldrich:7101-31-7(sigmaaldrich)
  • Alfa Aesar:Dimethyl diselenide, 99%(7101-31-7)
  • 图谱信息:二甲基二硒醚(7101-31-7)核磁图( 1 HNMR)
  • MSDS 信息:Dimethyldiselenide(7101-31-7).msds
  • MOL 文件:7101-31-7.mol
  • 二甲基二硒醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D3290 二甲基二硒醚 Dimethyl Diselenide 5G 1240元 2014/06/02 D3290 二甲基二硒醚 Dimethyl Diselenide 1G 351元 2010/05/25 68119 Dimethyl diselenide, 99% 5g 2030元
  • TCI Shanghai:二甲基二硒醚 Dimethyl Diselenide,>;98.0%(GC)(7101-31-7)
  • 敏感性:Air & Moisture Sensitive

系列性分类


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