tert-Butylzinc bromide solution 叔丁基溴化锌

CAS 7565-59-5 MFCD00671989

化学结构图

7565-59-5
SMILES: C[C-](C)C.[Zn+]Br

化学属性

Mol. FormulaC4H9BrZn
Mol. Weight137
Density0.966 g/mL at 25 °C
TSCANo

别名和识别编码

Chemical Nametert-Butylzinc bromide, 0.50 M in THF
MDL NumberMFCD00671989
CAS Number7565-59-5
PubChem Substance ID4616895
Synonym 叔丁基溴化锌 溶液
Chemical Name Translation叔丁基溴化锌
LabNetwork Molecule IDLN01320204
InChIInChI=1S/C4H9.BrH.Zn/c1-4(2)3;;/h1-3H3;1H;/q-1;;+2/p-1
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分类

  • {SNA} Alkyl, Chemical Synthesis, Organometallic Reagents, Organozinc Halides, Rieke and Organozinc Reagents

安全信息

WGK Germany3
Hazard Codes F,Xn Xn
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中,保持干燥;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Risk Statements
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R14 Reacts violently with water 遇水会猛烈反应
  • R22 Harmful if swallowed 吞咽有害
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R11 Highly flammable 非常易燃
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
  • R37 Irritating to respiratory system 刺激呼吸道
  • R34 Causes burns 会导致灼伤
Packing GroupII
UN Number UN3399
Storage condition Air Sensitive
Precautionary statements
  • P305+P351+P338
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
Signal word Warning
Hazard statements
  • H351 Suspected of causing cancer 怀疑致癌
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
GHS Symbol

系列性分类


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