Allyltriphenyltin 烯丙基三苯基锡

CAS 76-63-1 MFCD00048162

化学结构图

76-63-1
SMILES: C=CC[Sn](c1ccccc1)(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC21H20Sn
Mol. Weight391.10
Melting Point72.0 to 76.0 deg-C
Flash Point>100
Density1,07 g/cm3

别名和识别编码

Chemical NameAllyltriphenyltin
MDL NumberMFCD00048162
CAS Number76-63-1
Reaxys-RN3612762
Beilstein Registry Number16(4)1592
PubChem Substance ID6452
Synonym Triphenyl(2-propenyl)stannane Dowco 187 3-(Triphenylstannyl)-1-propene; Allyltriphenyltin; Triphenyl(2-propenyl)stannane Triphenyl(allyl)stannane dowco187 2-丙烯基-三苯基锡 丙烯基三苯基锡 Allyltriphenyltin Allyltriphenylstannane Triphenylallyltin(IV) 丙烯基三苯基锡 Stannane, triphenyl-2-propenyl- 2-Propenyl-triphenylstannane, Allyltriphenyltin 丙烯基三苯基锡,97% Triphenyl-2-propenylstannane ENT 50909 ALLYLTRIPHENYLTIN Allyltriphenyltin,97% triphenyl-2-propenyl-stannan 烯丙基三苯基锡 ent50909 TINALLYLTRIPHENYL allyltriphenylstannane TRIPHENYLALLYLTIN 2-propenyl-triphenylstannane allyltriphenyl-stannan 3-(Triphenylstannyl)-1-propene
EC Number200-975-4
Chemical Name Translation烯丙基三苯基锡
InChIKeyNDUYAGLANMHJHF-UHFFFAOYSA-N
Wiswesser Line Notation1U2-SN-R&R&R
LabNetwork Molecule IDLN01740084
InChIInChI=1S/3C6H5.C3H5.Sn/c3*1-2-4-6-5-3-1;1-3-2;/h3*1-5H;3H,1-2H2;
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分类

  • Chemical Synthesis, Organometallic Reagents, Organotin, Organotins
  • {SA} Chemical Synthesis, Organometallic Reagents, Organotin, Organotins

相关文献及参考

  • J. Am. Chem. Soc. 103 , 1969, (1981)
  • Beil. 16 ,IV,1592
  • Fieser 13 ,14 / Fieser 14 ,20
  • FT-IR 2 (3), 4501:D / FT-NMR 1 (3), 748:C / RegBook 1 (2), 3067:C / Sax 6 , 173 / Structure Index 1 , 486:C:3

安全信息

RTECSWH6705000
UN Number 3146 UN 3146 6.1/PG 3
Signal word Danger
Hazard statements
  • H301+H311+H331
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P302+P350
  • P337+P313
  • P403+P233
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P312+P361+P364
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P304+P340+P311
WGK Germany3
GHS Symbol
Hazard Codes T,N
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Packing GroupIII
Hazard Class6.1
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R50/53 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02200

其他信息

  • TCI Shanghai:烯丙基三苯基锡 Allyltriphenyltin,>;95.0%(W)(76-63-1)
  • Sigma Aldrich:76-63-1(sigmaaldrich)
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • 毒性分级:高毒
  • 可燃性危险特性:可燃;燃烧产生刺激烟雾
  • 丙烯基三苯基锡,97%价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A1491 烯丙基三苯基锡 Allyltriphenyltin 5G 313元 2014/06/02 A1491 烯丙基三苯基锡 Allyltriphenyltin 25G 950元
  • MOL 文件:76-63-1.mol
  • TSCA:No
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • 职业标准:TWA 0.1 毫克(锡)/立方米; STEL 0.2 毫克(锡)/立方米
  • 急性毒性:静脉-小鼠 LD50: 100 毫克/公斤
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organotin 有机锡
  4. Organotins - Organotin
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物

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