Arsine 砷烷

CAS 7784-42-1 MFCD00003432

化学结构图

7784-42-1
SMILES: [AsH3]

化学属性

Mol. FormulaAsH3
Mol. Weight77.95
Solubility溶于水，微溶于乙醇、碱液。

别名和识别编码

Chemical NameArsine
Synonym Arsenic trihydride Arsine (AsH3) Arsenic hydride AsH3 Arseniuretted hydrogen arsane Arsenic(III) hydride 胂 ARSENE Arsenowodor 砷化氢 arsine Arsenic hydride (AsH3) 砷烷 AsH3 三氢化砷 ARSINE Hydrogen arsenide Arsine INORGANICARSINE Arsenous hydride arsenic (III) hydride 砷化三氢 Arsenic hydrid Arsenwasserstoff
Chemical Name Translation砷烷
CAS Number7784-42-1
Wiswesser Line NotationAS H3
PubChem Substance ID23969
InChIInChI=1S/AsH3/h1H3
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分类

  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: II/24A Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, l-type, Centrifugal Distortion and Related Constants of Diamagnetic Diatomic, Linear, and Symmetric Top Molecules Author: Demaison, J.; Hübner, H.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24A Year: 1998 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-63267-0 ISBN: 978-3-540-63267-2 Internet Resource: DOI:10.1007/b60165 RefComment: VIII, 286 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24A contains the general introduction and tables of rotational and centrifugal distortion constants of diamagnetic diatomic, linear and symmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
  • Short: II/24C Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Interaction Constants of Diamagnetic Molecules Author: Demaison, J.; Hübner, H.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24C Year: 2002 Keyword: Atoms; Molecules and Cluster; Physi

安全信息

Hazard Codes F+,T+,N
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Risk Statements
  • R26 Very toxic by inhalation 吸入极毒
  • R12 Extremely flammable 极端易燃
  • R48/20
  • R50/53
UN Number 2188
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品
RTECSCG6475000 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 390 mg/m3/10M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB158-508

{haz

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Mammal - domestic
DOSE/DURATION           : 3 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BJPCAL British Journal of Pharmacology and Chemotherapy.  (London, UK)
   V.1-33, 1946-68.  For publisher information, see BJPCBM.
   Volume(issue)/page/year: 1,287,1946

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : 150 mg/m3/20M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1306,1935

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : 2 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BJPCAL British Journal of Pharmacology and Chemotherapy.  (London, UK)
   V.1-33, 1946-68.  For publisher information, see BJPCBM.
   Volume(issue)/page/year: 1,287,1946

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : I

其他信息

  • 用途:用于砷有机化合物的合成
  • 外观性质:无色气体，有大蒜臭味。
  • 水中溶解度(g/100ml):每100毫升水中的溶解克数: 8×10-2/20℃
  • 稳定性:Stable, but pyrophoric. Capable of detonation with some initiators. Flammable. Incompatible with oxidizing agents, chlorine, nitric acid.
  • MOL 文件:7784-42-1.mol
  • HazardClass:2.3

系列性分类

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