-甲基-N-羟乙基苯胺 N-甲基-N-羟乙基苯胺

CAS 93-90-3 MFCD00020572

化学结构图

93-90-3
SMILES: CN(CCO)c1ccccc1

化学属性

Mol. FormulaC9H13NO
Mol. Weight151.21
Refractive index1.5690 to 1.5730
Boiling Point262.2 °C at 760 mmHg
Density1.06
Flash Point>110°C
Appearance 浅黄色油状透明液体。 微溶于水,溶于乙醇和乙醚。
Solubility微溶于水,溶于乙醇和乙醚。
Melting Point77 °C

别名和识别编码

Chemical Name-甲基-N-羟乙基苯胺
MDL NumberMFCD00020572
CAS Number93-90-3
PubChem Substance ID62340
EC Number202-285-9
Synonym 2-(Methyl(phenyl)amino)ethanol {LY} 2-(Methyl(phenyl)amino)ethanol {} {LY} 2-(Methyl(phenyl)amino)ethanol {} {} {LY} 2-(Methyl(phenyl)amino)ethanol {} {} {} {LY} 2-(Methyl(phenyl)amino)ethanol {} {} {} {} {LY} 2-(Methyl(phenyl)amino)ethanol {} {} {} {} {} {LY} 2-(Methyl(phenyl)amino)ethanol {} {} {} {} {} {} {LY} 2-(Methyl(phenyl)amino)ethanol {} {} {} {} {} {} {} {LY} 2-(Methyl(phenyl)amino)ethanol {} {} {} {} {} {} {} {} {LY} 2-(Methyl(phenyl)amino)ethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Methyl(phenyl)amino)ethanol {} {} {} {} {} {} {} {} {} {} {LY} 2-(Methyl(phenyl)amino)ethanol {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Methyl(phenyl)amino)ethanol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Methyl(phenyl)amino)ethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Methyl(phenyl)amino)ethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Methyl(ph
Beilstein Registry Number2803140
Reaxys-RN2803140
Chemical Name TranslationN-甲基-N-羟乙基苯胺
Wiswesser Line NotationQ2N1&R
LabNetwork Molecule IDLN00221395
InChIInChI=1S/C9H13NO/c1-10(7-8-11)9-5-3-2-4-6-9/h2-6,11H,7-8H2,1H3
Canonical SMILESCN(CCO)C1=CC=CC=C1
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分类

  • {SNA} Amino Alcohols, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H303+H313
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSKL7175000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Signal word Warning
Hazard Codes Xi
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 3250 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 4,119,1951

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2830 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 4,119,1951

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • TCI Shanghai:2-(N-甲基苯胺基)乙醇 2-(N-Methylanilino)ethanol,>;97.0%(T)(93-90-3)
  • 用途二:染料阳离子蓝X-GRRL、阳离子桃红FG的中间体。
  • 用途一:用作染料中间体
  • 方法一:由N-甲基苯胺与环氧乙烷经羟基化制得。将105kgN-甲基苯胺加入反应锅,加热至130℃,通氮气置换空气。在150-152℃,约0.3MPa以下,分批通入50kg环氧乙烷。加毕,在150-155℃保温3h,得150-155kgN-羟乙基-N-甲基苯胺。
  • 下游产品:阳离子蓝X-GRRL
  • 检测方法:HPLC
  • Sigma Aldrich:93-90-3(sigmaaldrich)
  • 上游原料:正丁醇 --> 碘化钾 --> 2-氯乙醇 --> N-甲基苯胺
  • N-甲基-N-羟乙基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0359 2-(N-甲基苯胺基)乙醇 2-(N-Methylanilino)ethanol 500ML 1160元 2014/06/02 H0359 2-(N-甲基苯胺基)乙醇 2-(N-Methylanilino)ethanol 25ML 347元
  • N-甲基-N-羟乙基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 H0359 2-(N-甲基苯胺基)乙醇 2-(N-Methylanilino)ethanol 500ML 948元 2011/04/16 H0359 2-(N-甲基苯胺基)乙醇 2-(N-Methylanilino)ethanol 25ML 286元
  • MSDS 信息:2-(N-Methylanilino)ethanol(93-90-3).msds
  • MOL 文件:93-90-3.mol

系列性分类


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