Quinoline-8-boronic acid 喹啉-8-硼酸

CAS 86-58-8 MFCD01114698

化学结构图

86-58-8
SMILES: OB(O)c1cccc2cccnc12

化学属性

Mol. FormulaC9H8BNO2
Mol. Weight172.98
Density1.422
Melting Point>300°C
TSCANo
Boiling Point160-165 °C at 760 mmHg

别名和识别编码

Chemical NameQuinoline-8-boronic acid
CAS Number86-58-8
Alfabeta NameQUINOLINEBORONICACID 8-
MDL NumberMFCD01114698
Synonym 8-Quinolineboronic acid {LY} 8-Quinolineboronic acid {} {LY} 8-Quinolineboronic acid {} {} {LY} 8-Quinolineboronic acid {} {} {} {LY} 8-Quinolineboronic acid {} {} {} {} {LY} 8-Quinolineboronic acid {} {} {} {} {} {LY} 8-Quinolineboronic acid {} {} {} {} {} {} {LY} 8-Quinolineboronic acid {} {} {} {} {} {} {} {LY} 8-Quinolineboronic acid {} {} {} {} {} {} {} {} {LY} 8-Quinolineboronic acid {} {} {} {} {} {} {} {} {} {LY} 8-Quinolineboronic acid {} {} {} {} {} {} {} {} {} {} {LY} 8-Quinolineboronic acid {} {} {} {} {} {} {} {} {} {} {} {LY} 8-Quinolineboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 8-Quinolineboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 8-Quinolineboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 8-Quinolineboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 8-Quinolineboronic acid
EC Number000-000-0
Beilstein Registry Number147522
PubChem Substance ID2734380
Merck Number8069
Chemical Name Translation喹啉-8-硼酸
Reaxys-RN147522
LabNetwork Molecule IDLN00116871
InChIInChI=1S/C9H8BNO2/c12-10(13)8-5-1-3-7-4-2-6-11-9(7)8/h1-6,12-13H
Canonical SMILESOB(O)C1=CC=CC2=C1N=CC=C2
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分类

  • {SNA} Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Heteroaryl Boronic Acids, Organometallic Reagents

产品应用

  • Reactant involved in:
  • 1 C-H and C-S bond activations
  • 2Synthesis of pyridazine via sequential amination / Suzuki coupling / alkylation reactions
  • 3Suzuki-Miyaura coupling reactions for synthesis of biaryl monophosphorus ligands, fused tricyclic oxa-quinolones, or substituted β-amino acids

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 上游原料:乙醚 --> 四氢呋喃 --> 正丁基锂 --> 乙腈 --> 硼酸三甲酯 --> 溴化铜 --> 亚硝酸特丁酯 --> 8-溴喹啉 --> 8-氨基喹啉
  • MOL 文件:86-58-8.mol
  • Alfa Aesar:喹啉-8-硼酸,99% Quinoline-8-boronic acid, 99%(86-58-8)
  • 检测方法:HPLC
  • Sigma Aldrich:86-58-8(sigmaaldrich)
  • Acros Organics:8-喹啉硼酸 8-Quinoline boronic acid, 96%(86-58-8)
  • 喹啉-8-硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 359670010 喹啉-8-硼酸 8-Quinoline boronic acid 96% 1 GR 2706元 2010/06/21 359672500 喹啉-8-硼酸 8-Quinoline boronic acid 96% 250 MG 983元 2010/05/25 L19640 喹啉-8-硼酸, 99% Quinoline-8-boronic acid, 99% 250mg 1326元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Aromatic alcohols 芳香醇

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