3-Amino-4-methylpyridine 3-氨基-4-甲基吡啶

CAS 3430-27-1 MFCD00128871

化学结构图

3430-27-1
SMILES: Cc1ccncc1N

化学属性

Mol. FormulaC6H8N2
Mol. Weight108.14
Boiling Point261.3°C at 760 mmHg
Melting Point102-106°C
Density1.422
TSCANo
Stability易吸湿
Flash Point254°C
Appearance 原白色结晶

别名和识别编码

Chemical Name3-Amino-4-methylpyridine
CAS Number3430-27-1
Alfabeta NameAMINOMETHYLPYRIDINE 34---
MDL NumberMFCD00128871
EC Number250-023-7
Beilstein Registry Number107792
Synonym 3-Amino-4-methylpyridine {LY} 3-Amino-4-methylpyridine {} {LY} 3-Amino-4-methylpyridine {} {} {LY} 3-Amino-4-methylpyridine {} {} {} {LY} 3-Amino-4-methylpyridine {} {} {} {} {LY} 3-Amino-4-methylpyridine {} {} {} {} {} {LY} 3-Amino-4-methylpyridine {} {} {} {} {} {} {LY} 3-Amino-4-methylpyridine {} {} {} {} {} {} {} {LY} 3-Amino-4-methylpyridine {} {} {} {} {} {} {} {} {LY} 3-Amino-4-methylpyridine {} {} {} {} {} {} {} {} {} {LY} 3-Amino-4-methylpyridine {} {} {} {} {} {} {} {} {} {} {LY} 3-Amino-4-methylpyridine {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Amino-4-methylpyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Amino-4-methylpyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Amino-4-methylpyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Amino-4-methylpyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Amin
Reaxys-RN107792
PubChem Substance ID87559034
Chemical Name Translation3-氨基-4-甲基吡啶
LabNetwork Molecule IDLN00223154
InChIInChI=1S/C6H8N2/c1-5-2-3-8-4-6(5)7/h2-4H,7H2,1H3
Canonical SMILESCC1=C(N)C=NC=C1
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分类

  • {SNA} Building Blocks, C6, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines

相关文献及参考

  • Ortho-lithiation with t-BuLi of the Boc-protected amine followed by addition of a Weinreb amide gave the 2-alkyl substituted 5-azaindole in good yield: J. Heterocycl. Chem., 29, 359 (1992), whereas DMF gave 6-azaindole in high yield: Synthesis, 877 (1996). 2-Substituted 6-azaindoles have also been synthesized in one step by direct dilithiation with s-BuLi, followed by reaction with an ester: J. Org, Chem., 70, 6512 (2005).

安全信息

Warnings TOXIC
Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P330
  • P302+P352+P312+P361+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P307+P311
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Packing GroupIII
UN Number 2811
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Hygroscopic {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from li
Hazard statements
  • H301+H311
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes 6.1 T,Xn Xn
Hazard Class6.1

其他信息

  • MOL 文件:3430-27-1.mol
  • Alfa Aesar:3-氨基-4-甲基吡啶,98% 3-Amino-4-methylpyridine, 98%(3430-27-1)
  • 检测方法:HPLC,NMR,GC
  • Sigma Aldrich:3430-27-1(sigmaaldrich)
  • 3-氨基-4-甲基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A1957 3-氨基-4-甲基吡啶 3-Amino-4-methylpyridine 5G 196元 2014/06/02 A1957 3-氨基-4-甲基吡啶 3-Amino-4-methylpyridine 25G 592元 2010/05/25 L19730 3-氨基-4-甲基吡啶, 98% 3-Amino-4-methylpyridine, 98% 5g 774元
  • Hazard Note:Toxic
  • 下游产品:2-溴-3-氨基-4-甲基吡啶 --> 2-氯-3-氨基-4-甲基吡啶
  • TCI Shanghai:3-氨基-4-甲基吡啶 3-Amino-4-picoline,>;98.0%(GC)(T)(3430-27-1)

系列性分类

  1. C6 to C7 - Pyridines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

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