Sulfuryl fluoride 硫酰氟

CAS 2699-79-8 MFCD00153272

化学结构图

2699-79-8
SMILES: O=S(=O)(F)F

化学属性

Mol. FormulaF2O2S
Mol. Weight102.06
Melting Point-121,4°C
Boiling Point-55,2°C
Solubility溶于乙醇、苯、四氯化碳。
pH:A

别名和识别编码

Chemical NameSULFURYL FLUORIDE
Synonym Fluorure de sulfuryle SO2F2 SULFURYL FLUORIDE SULPHURYL FLUORIDE Schwefeldioxiddifluorid Sulfonyl fluoride Sulfur difluoride dioxide Sulfur dioxide difluoride Sulfur fluoride oxide (SF2O2) Sulfur fluoride oxide (SO2F2) Sulfur oxide fluoride (SF2O2) Sulfur oxyfluoride (SO2F2) Sulfuric oxyfluoride Sulfuryl difluoride Sulfuryl fluoride Sulfuryldifluorid Sulfurylfluorid Sulphuryl fluoride Vikane Vikane Gas Fumigant Vikane fumigant fluorodesulfurilo fluoruredesulfuryle fluoruredesulfuryle(french) sulfonyl difluoride sulfonyl fluoride sulfonylfluoride sulfurdifluoridedioxide
CAS Number2699-79-8
EC Number220-281-5
MDL NumberMFCD00153272
Chemical Name Translation硫酰氟
Wiswesser Line NotationS O2-F2
PubChem Substance ID17607
InChIInChI=1S/F2O2S/c1-5(2,3)4
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分类

  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: II/25A Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25A Year: 1998 Keyword: Free Polyatomic Molecules; Inorganic Molecules; Molecules ISBN: 3-540-61713-2 ISBN: 978-3-540-61713-6 Internet Resource: DOI:10.1007/b59072 RefComment: VII, 359 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvent

安全信息

Hazard Codes C,N,T
Hazard Class2.3
UN Number 2191
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S63
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R23 Toxic by inhalation 吸入有毒
  • R48/20
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
Warnings 危化品目录(2015)
RTECSWT5075000
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 991 ppm/4H
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - acute pulmonary edema
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   7,664,1986

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 5000 ppm/1H
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   AMPMAR Archives des Maladies Professionnelles de Medecine du Travail et de
   Securite Sociale.  (SPPIF, B.P.22, F-41353 Vineuil, France)  V.7-    1946-
   Volume(issue)/page/year: 34,581,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DOWCC* Dow Chemical Company Reports.  (Dow Chemical USA, Health and
   Environment Research, Toxicology Research Lab., Midland, MI 48640)

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSU

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 225 ppm/6H
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   13,79,1989

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE                    : 225 ppm/6H
SEX/DURATION            : female 6-18 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - cardiovascular
   (circulatory) system
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   13,79,1989

Hazard statements
  • H280 Contains gas under pressure; may explode if heated 内含高压气体,遇热可能爆炸。
  • H330 Fatal if inhaled 吸入致命
  • H331 Toxic if inhaled 吸入中毒
  • H370 Causes damage to organs 导致器官损伤
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P316
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P307+P311
  • P308+P316
  • P309+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P316
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P410+P403
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Restrict 危险品

其他信息

  • 用途一:用于熏蒸建筑物、车船运输工具及木材制品,防治白蚁、飞蠊、家天牛、鼠类等
  • 外观性质:无色、无臭气体。
  • 毒性分级:高毒
  • 下游产品:安塞蜜 --> 1,1-二氟乙烷
  • 灭火剂:化学干粉、二氧化碳、喷水、聚合泡?i
  • 职业标准:TWA 20 毫克/立方米; STEL 40 毫克/立方米
  • 可燃性危险特性:不燃; 火场释放硫氧化物, 氟化物气体
  • 上游原料:氯 --> 氢氟酸 --> 二氧化硫
  • Hazard Note:Corrosive
  • 类别:压缩气体和液化气体
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • 急性毒性:吸入-大鼠 LC50: 991 PPM/4小时; 口服-大鼠 LD50: 100 毫克/公斤
  • MOL 文件:2699-79-8.mol
  • MSDS 信息:硫酰氟(2699-79-8).msds

系列性分类


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