Benzyl 2-chloroacetate 氯乙酸苄酯

CAS 140-18-1 MFCD00157062

化学结构图

140-18-1
SMILES: O=C(CCl)OCc1ccccc1

化学属性

Mol. FormulaC9H9ClO2
Mol. Weight184.62
Refractive index1.5240 to 1.5270
Boiling Point132°C/12mmHg
Density1.215 g/mL at 25 °C(lit.)
Solubility不溶
Flash Point>;230 °F

别名和识别编码

Chemical NameBenzyl 2-chloroacetate
Synonym chloro-acetic acid benzyl ester benzylmonochloracetate 氯乙酸苄酯 Monochloroacetate Benzyl 2-chloroacetate 2-CHLORO ACETIC ACID BENZYLESTER monochloroacetate CHLOROACETIC ACID BENZYL ESTER Chloroacetic acid, benzyl ester benzyl-alpha-chloroacetate chloro-aceticacibenzylester Benzyl-alpha-chloroacetate BENZYL 2-CHLOROACETATE benzyl 2-chloroacetate BENZYL CHLOROACETATE benzyl chloracetate Benzyl monochloroacetate Benzyl monochloracetate Chloressigsäurebenzylester Phenylmethyl chloroacetate benzyl chloroacetate BENZYL-(CHLORACETAT) Acetic acid, chloro-, benzyl ester Acetic acid, chloro-, phenylmethyl ester phenylmethylchloroacetate Benzyl α-chloroacetate AKOS B029322 Phenylmethyl 2-chloroacetate Benzyl chloroacetate Benzyl-(chloracetat) phenylmethyl chloroacetate chloro-aceticaciphenylmethylester 氯乙酸苯甲酯
MDL NumberMFCD00157062
CAS Number140-18-1
PubChem Substance ID87566283
EC Number205-400-0
Chemical Name Translation氯乙酸苄酯
Reaxys-RN2091502
Beilstein Registry Number6(4)2264
InChIKeySOGXBRHOWDEKQB-UHFFFAOYSA-N
Wiswesser Line NotationG1VO1R
LabNetwork Molecule IDLN00223535
InChIInChI=1S/C9H9ClO2/c10-6-9(11)12-7-8-4-2-1-3-5-8/h1-5H,6-7H2
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ester; 1fragment
  • {SNA} Building Blocks, C8 to C9, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

相关文献及参考

  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSAF8750000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard Codes Xi
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 8,99,1956

其他信息

  • MOL 文件:140-18-1.mol
  • 可燃性危险特性:可燃; 燃烧产生有毒氯化物烟雾
  • MSDS 信息:Benzyl 2-chloroacetate(140-18-1).msds
  • 上游原料:二氯甲烷 --> 吡啶 --> 氯乙酰氯 --> 苄醇
  • Sigma Aldrich:140-18-1(sigmaaldrich)
  • 毒性分级:中毒
  • Acros Organics:氯乙酸苄酯 Benzyl chloroacetate, 98%(140-18-1)
  • 急性毒性:腹腔-小鼠 LDL0: 500 毫克/公斤
  • 储运特性:通风低温干燥
  • 氯乙酸苄酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1265 氯乙酸苄酯 Benzyl Chloroacetate 25G 767元 2014/06/02 C1265 氯乙酸苄酯 Benzyl Chloroacetate 250G 4800元 2010/06/21 336160050 氯乙酸苄酯 Benzyl chloroacetate 98% 5 ML 351元
  • TCI Shanghai:氯乙酸苄酯 Benzyl Chloroacetate,>;97.0%(GC)(140-18-1)
  • 图谱信息:氯乙酸苄酯(140-18-1)核磁图( 1 HNMR) 氯乙酸苄酯(140-18-1)核磁图( 13 CNMR) 氯乙酸苄酯(140-18-1)质谱(MS) 氯乙酸苄酯(140-18-1)红外图谱(IR1)
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C8 to C9 - Esters

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