(Benzyloxycarbonylmethyl)Triphenylphosphonium Bromide (苄氧羰基甲基)三苯基溴化
CAS 78385-36-1 MFCD00191780
化学结构图
SMILES: [Br-].O=C(C[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)OCC1C=CC=CC=1
化学属性
| Mol. Formula | C6H5CH2O2CCH2P(C6H5)3Br |
|---|---|
| Mol. Weight | 493.37 |
| Melting Point | 124 °C (dec.)(lit.) |
别名和识别编码
| Chemical Name | (Benzyloxycarbonylmethyl)Triphenylphosphonium Bromide |
|---|---|
| MDL Number | MFCD00191780 |
| PubChem Substance ID | 24866100 |
| CAS Number | 78385-36-1 |
| Chemical Name Translation | (苄氧羰基甲基)三苯基溴化 |
| Synonym | (苄氧羰基甲基)三苯基溴化膦 |
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
相关文献及参考
- 1. Saunders, L. B.; et al. Org. Lett. 12 , 4800, (2010)
- 2. Castaneda, F.; et al. Phosph. Sulfur Relat. Elem. 183 , 1188, (2008)
- 3. Cabral dos Santos, L.; et al. Heterocycles 73 , 751, (2007)
- 4. Ortega-Caballero, F.; Bols, M. Can. J. Chem. 84 , 650, (2006)
- 5. Watanabe, M.; et al. Z. Naturforsch. B 60 , 909, (2005)
- 6. Hum, G.; et al. Bioorg. Med. Chem. Lett. 12 , 3471, (2002)
- FT-IR 2 (2), 3339:C / Structure Index 1 , 357:E:1
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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