Diallyl Diisopropylphosphoramidite 二烯丙基二异丙基亚磷酰胺

CAS 126429-21-8 MFCD00216647

化学结构图

126429-21-8
SMILES: C=CCOP(OCC=C)N(C(C)C)C(C)C

化学属性

Mol. Formula[(CH3)2CH]2NP(OCH2CH=CH2)2
Mol. Weight245.30
Refractive indexn20/D 1.456(lit.)
Boiling Point130 °C(lit.)
Density0.928 g/mL at 25 °C(lit.)

别名和识别编码

Chemical NameDiallyl Diisopropylphosphoramidite
Synonym N,N-Bis(1-methylethyl)phosphoramidous acid di-2-propenyl ester Diallyloxy(diisopropylamino)phosphine 己二烯 N,N-二异丙基亚磷酰胺
CAS Number126429-21-8
PubChem Substance ID4686855
Beilstein Registry Number4383514
MDL NumberMFCD00216647
Chemical Name Translation二烯丙基二异丙基亚磷酰胺
LabNetwork Molecule IDLN02151321
InChIInChI=1S/C12H24NO2P/c1-7-9-14-16(15-10-8-2)13(11(3)4)12(5)6/h7-8,11-12H,1-2,9-10H2,3-6H3
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分类

  • {SA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphoramidites, Phosphorus Compounds

相关文献及参考

  • 1. T. Nishi, et al., Bioconjug. Chem. 2 , 368-372, (2011)
  • 2. Y. Kagoshima, et al., Chem. Pharm. Bull. 58 , 794-804, (2010)
  • 3. T. Takeuchi, et al., Org. Lett. 8 , 5307-5310, (2006)
  • 4. P. B. Brady, et al., Tetrahedron Lett. 50 , 975-978, (2009)
  • 5. S. Tanaka, et al., Tetrahedron Lett. 48 , 7320-7322, (2007)
  • 6. S. Knapp and K. Ajayi, Tetrahedron Lett. 48 , 1945-1949, (2007)
  • FT-IR 2 (1), 1550:B / Structure Index 1 , 169:D:4

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphoramidites - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphoramidites - Phosphorus Compounds

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