1-Benzyl-4-piperidinecarboxaldehyde, 97% 1-苄基-4-哌啶甲醛

CAS 22065-85-6 MFCD02258902

化学结构图

22065-85-6
SMILES: O=CC1CCN(CC2C=CC=CC=2)CC1

化学属性

Mol. FormulaC13H17NO
Mol. Weight203
Refractive index1.5340 to 1.5390
Boiling Point315
Density1.026
Flash Point>110°(230°F)
TSCANo

别名和识别编码

Chemical Name1-Benzyl-4-piperidinecarboxaldehyde, 97%
CAS Number22065-85-6
Alfabeta NameBENZYLPIPERIDINECARBALDEHYDE 14---
MDL NumberMFCD02258902
Synonym 1-(Phenylmethyl)-4-piperidinecarboxaldehyde 1-(Phenylmethyl)-4-piperidinecarboxaldehyde 1-Benzyl-4-formylpiperidine 1-Benzylisonipecotaldehyde 1-Benzyl-4-formylpiperidine 1-Benzylisonipecotaldehyde 1-Benzylpiperidine-4-carbaldehyde 1-benzyl-4-piperidinecarboxaldehyde, 1-Benzyl-4-formylpiperidine, 1-Benzylisonipecotaldehyde 1-苄基-4-哌啶甲醛 4-Formyl-1-benzylpiperidine N-(Phenylmethyl)piperidine-4-carboxaldehyde N-Benzyl-4-formylpiperidine
PubChem Substance ID87560454
EC Number244-757-7
Reaxys-RN1454307
Beilstein Registry Number1454307
Chemical Name Translation1-苄基-4-哌啶甲醛
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分类

  • {SNA} Aldehydes, Building Blocks, C13, C13-C60, Carbonyl Compounds, Chemical Synthesis, Heterocyclic Building Blocks, Organic Building Blocks, Piperidines
  • Aldehydes, Building Blocks, C13, C13-C60, Carbonyl Compounds,

相关文献及参考

  • 1. D. Li, et al., J. Am. Chem. Soc. 133 , 5672-5675, (2011)
  • 2. E. Riva, et al., Tetrahedron 66 , 3242-3247, (2010)
  • 3. P. La Beaume, et al., Tetrahedron Lett. 51 , 1906-1909, (2010)
  • 4. A. Piergentili, et al., J. Med. Chem. 53 , 1261-1269, (2010)
  • 5. R. J. R. Rao, et al., Synth. Commun. 37 , 2847-2853, (2007)
  • 6. T. K. Sasikumar, et al., Bioorg. Med. Chem. Lett. 16 , 4917-4921, (2006)
  • 7. R. Janaki Rama Rao, et al., Efficient and Industrially Viable Synthesis of Donepezil Synth. Commun. 37 , 2847-2853, (2007)

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard Codes 6.1 T
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P302+P350
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Signal word Danger
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Storage condition Air Sensitive 0-10°C
UN Number 2810
Packing GroupIII

系列性分类


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