Musk Ambrette 葵子麝香

CAS 83-66-9 MFCD00024268

化学结构图

83-66-9
SMILES: COc1c(C(C)(C)C)cc([N+](=O)[O-])c(C)c1[N+](=O)[O-]

化学属性

Mol. FormulaC12H16N2O5
Mol. Weight268.27
Appearance 浅黄色片状结晶。熔点84-86℃，沸点185℃（2.13kPa）。溶于乙醚、甲醇、微溶于乙醇。不溶于水，闪点65℃。
Boiling Point185°C/16mmHg(lit.)
Melting Point85.0 to 87.0 deg-C

别名和识别编码

Chemical NameMusk Ambrette
Synonym 1-(1 1-(1,1-Dimethylethyl)-2-methoxy-4-methyl-3, 1-(1,1-Dimethylethyl)-2-methoxy-4-methyl-3,5-dinitro-benzene 1-(1,1-Dimethylethyl)-2-methoxy-4-methyl-3,5-dinitrobenzol 1-(tert-butyl)-2-methoxy-4-methyl-3,5-dinitrobenzene 1-(TER 1-1,1-Dimethylethyl-2-methoxy-4-methyl-3,5-dinitro-benzene 1-tert-Butyl-2-methoxy-4-methyl-3,5-dinitro-benzene 1-tert-Butyl-2-methoxy-4-methyl-3,5-dinitrobenze 2,4-Dinitro-3-methyl-6-tert-butylanisole 2,6-DINITRO-4-TERT-BUTYL-3-METHOXYTOLUENE 2,6-Dini 2,6-Dinitro-3-methoxy-4-tert-butyltoluene 2-methoxy-3,5-dinitro-4-methyl-t-butylbenzene 2-tert-Butyl-4,6-dinitro-5-methylanisole 3-tert-Butyl-2,6-dinitro-3-methoxytoluene 4-tert-Butyl-2,6-dinitro-3-methoxytoluene 4-
MDL NumberMFCD00024268
CAS Number83-66-9
EC Number201-493-7
Chemical Name Translation葵子麝香
Reaxys-RN1889437
PubChem Substance ID6753
Wiswesser Line NotationWNR B1 DO1 CNW EX1&1&1
Beilstein Registry Number1889437
LabNetwork Molecule IDLN00466174
InChIInChI=1S/C12H16N2O5/c1-7-9(13(15)16)6-8(12(2,3)4)11(19-5)10(7)14(17)18/h6H,1-5H3
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信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ether; 1fragment

相关文献及参考

  • Short: IV/1a Title: Densities of Liquid Systems: Nonaqueous Systems and Ternary Aqueous Systems Author: Lacmann, R.; Synowietz, C. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/1a Year: 1974 ISBN: 3-540-06269-6 ISBN: 978-3-540-06269-1 Internet Resource: DOI:10.1007/b20003 RefComment: X, 716 pages. Hardcover Abstract: Volume IV/1 contains information on the densities of liquid systems. It may be considered as a supplement to volume II/1 of the 6th Edition, which contains only a few data on nonaqueous systems. Data are not listed for all systems but primarily for those of greater interest where data for a larger range of concentrations were available.
  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.
  • Short: IV/20C Title: Vapor Pressure and Antoine Coefficients for Nitrogen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20C Year: 2001 Keyword: organic compounds; vapor pressure ISBN: 3-540-41060-0 ISBN: 978-3-540-41060-7 Internet Resource: DOI:10.1007/b88812 RefComment: VII, 197 pages
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSBZ8575000
Signal word
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P302+P350
  • P302+P352
  • P302+P352+P333+P313+P362+P364
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P333+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
UN Number 2811
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
GHS Symbol 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 13,875,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 339 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - respiratory stimulation
   Skin and Appendages - hair
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 2,327,1964

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 2 umol/plate
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   21,707,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   24,27,1986

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 10 mmol/L
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   21,707,1983

其他信息

  • 用途三:该品是硝基麝香中香气最优雅的品种，具有琥珀气息的麝香香气，国内外均大量生产，在硝基香料中产量最多、用途最广的香料品种之一，主要用于配制各种香料与香精中作定香剂，特别适用于高级香水。
  • 类别:有毒物质
  • FEMA:2758
  • 毒性分级:高毒
  • 急性毒性:口服-大鼠 LD50: 339 毫克/公斤
  • 2,6-二硝基-3-甲氧基-4-叔丁基甲苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1379 4-叔丁基-3-甲氧基-2,6-二硝基甲苯 4-tert-Butyl-3-methoxy-2,6-dinitrotoluene 500G 3170元 2014/06/02 B1379 4-叔丁基-3-甲氧基-2,6-二硝基甲苯 4-tert-Butyl-3-methoxy-2,6-dinitrotoluene 25G 347元
  • 上游原料:间甲酚 --> 间甲酚甲醚
  • 用途二:该品是硝基麝香中香气最优雅的品种，具有琥珀气息的麝香香气，国内外均大量生产，在硝基香料中产量最多、用途最广的香料品种之一，主要用于配制各种香料与香精中作定香剂，特别适用于高级香水。在一些加香品中的用量为：肥皂0.03-0.2%，去垢剂0.003-0.02，香水0.2-2.0%，香脂和洗液0.01-0.07%。
  • Sigma Aldrich:83-66-9(sigmaaldrich)
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • 图谱信息:2,6-二硝基-3-甲氧基-4-叔丁基甲苯(83-66-9)红外图谱(IR2) 2,6-二硝基-3-甲氧基-4-叔丁基甲苯(83-66-9)质谱(MS) 2,6-二硝基-3-甲氧基-4-叔丁基甲苯(83-66-9)Raman光谱 2,6-二硝基-3-甲氧基-4-叔丁基甲苯(83-66-9)红外图谱(IR1)
  • TCI Shanghai:2,6-二硝基-3-甲氧基-4-叔丁基甲苯 4-tert-Butyl-3-methoxy-2,6-dinitrotoluene,>;99.0%(GC)(83-66-9)
  • 灭火剂:水, 干粉, 二氧化碳, 泡沫
  • MSDS 信息:1-(tert-Butyl)-2-methoxy-4-methyl-3,5-dinitrobenzene(83-66-9).msds
  • 可燃性危险特性:热分解排出有毒氮氧化物烟雾
  • 方法一:以间甲酚为原料，用硫酸二甲酯甲基化，生成间甲酚甲醚，然后，间甲酚甲醚与异丁烯或叔丁醇反应生成叔丁基甲氧基甲苯，最后经硝化而得。
  • 2,6-二硝基-3-甲氧基-4-叔丁基甲苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 B1379 4-叔丁基-3-甲氧基-2,6-二硝基甲苯 4-tert-Butyl-3-methoxy-2,6-dinitrotoluene 500G 2610元 2011/04/16 B1379 4-叔丁基-3-甲氧基-2,6-二硝基甲苯 4-tert-Butyl-3-methoxy-2,6-dinitrotoluene 25G 286元
  • 用途一:用作香料及定香剂
  • MOL 文件:83-66-9.mol
  • 刺激数据:皮肤-兔 500 毫克/24小时 中度

系列性分类

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