Propargyl Chloroformate 炔丙基氯甲酸酯

CAS 35718-08-2 MFCD00270127

化学结构图

35718-08-2
SMILES: C=CCOC(=O)Cl

化学属性

Mol. FormulaHC≡CCH2OCOCl
Mol. Weight118.52
Refractive indexn20/D 1.435(lit.)
Boiling Point118-122 °C(lit.)
Vapor Pressure0.65 psi ( 20 °C)
Density1.215 g/mL at 25 °C(lit.)

别名和识别编码

Chemical NamePropargyl Chloroformate
Synonym 2-propynyl chloroformate Propargyl chloroformate {uni_hamburg} 炔丙基氯甲酸酯
PubChem Substance ID24869771
Beilstein Registry Number1745399
MDL NumberMFCD00270127
Chemical Name Translation炔丙基氯甲酸酯
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分类

  • {uni_hamburg} no charge; carbonyl chloride; 1fragment
  • {SA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
  • {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents, Functionalized Alkynes, Organic Building Blocks

相关文献及参考

  • Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
  • H302 Harmful if swallowed 吞食有害
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H311 Toxic in contact with skin 皮肤接触中毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Hazard Codes T
Risk Statements
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤
  • R22 Harmful if swallowed 吞咽有害
  • R23/24 Toxic by inhalation and in contact with skin 吸入及皮肤接触都有毒

系列性分类


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