Grubbs Catalyst 2ND Generation Grubbs2代催化剂

CAS 246047-72-3 MFCD03453237

化学结构图

246047-72-3
SMILES: C1CCC(P(C2CCCCC2)C2CCCCC2)CC1.Cc1cc(C)c(N2CCN(c3c(C)cc(C)cc3C)C2=[Ru](Cl)(Cl)=Cc2ccccc2)c(C)c1

化学属性

Mol. FormulaC46H65Cl2N2PRu
Mol. Weight848.97
Melting Point143.5-148.5 °C(lit.)

别名和识别编码

Chemical NameGrubbs Catalyst 2ND Generation
Synonym (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium 1,3-双(2,4,6-三甲基苯基)-2-(咪唑烷亚基)(二氯苯亚甲基)(三环己基膦)钌 苯亚甲基-1,3-双(2,4,6-三甲苯基)-2-(咪唑啉卡宾)(三环己基磷)二氯化钌 (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium 1,3-双(2,4,6-三甲基苯基)-2-(咪唑烷亚基)(二氯苯亚甲基)(三环己基膦)钌 Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II) Grubbs Catalyst™ C848 苯亚甲基-1,3-双(2,4,6-三甲苯基)-2-(咪唑啉卡宾)(三环己基磷)二氯化钌 1,3-双(2,4,6-三甲基苯基)-2-(咪唑烷亚基)(二氯苯亚甲基)(三环己基膦)钌;格拉布催化剂;Grubbs催化剂; 1,3-双(2,4,6-三甲基苯基)-2-(咪唑烷亚基)(二氯苯亚甲基)(三环己基膦)钌 Grubbs Catalyst™ C848 Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II) (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium 苯亚甲基-1,3-双(2,4,6-三甲苯基)-2-(咪唑啉卡宾)(三环己基磷)二氯化钌 Grubbs 2 代催化剂
MDL NumberMFCD03453237
CAS Number246047-72-3
Chemical Name TranslationGrubbs2代催化剂
PubChem Substance ID11147261
LabNetwork Molecule IDLN00226943
InChIInChI=1S/C21H26N2.C18H33P.C7H6.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h9-12H,7-8H2,1-6H3;16-18H,1-15H2;1-6H;2*1H;/q;;;;;+2/p-2
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Catalysts for Polymerization, Chemical Synthesis, Grubbs Catalyst Technology for Olefin Metathesis by Aldrich, Materials Science, Polymer Science, Reagents for Polymerization, Ring Opening Polymerization, Ruthenium Catalysts
  • {SNA} Catalysis, Catalysis and Inorganic Chemistry, Catalysts for Polymerization, Chemical Synthesis, Development Quantities for Research, Grubbs Catalyst Technology for Olefin Metathesis by Aldrich, Polymer Science, Reagents for Polymerization, Ring Opening Polymerization, Ruthenium Catalysts, 材料科学
  • {SA} Catalysis and Inorganic Chemistry, Catalysts for Polymerization, Chemical Synthesis, Ma

产品应用

  • Grubbs第二代催化剂
  • 和第一代催化剂相比更有活性，且具有更广泛的底物范围，包括对空间有要求或失活的烯烃，如1,1 - 二取代烯烃和α，β-不饱和羰基化合物

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
Hazard statements
  • H228 Flammable solid 易燃固体
Signal word Warning
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Hazard Codes F
Risk Statements
  • R11 Highly flammable 非常易燃
Storage condition 贮存温度:2-8°C

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Ruthenium 钌
  4. Metathesis Catalysts - Ruthenium
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Ruthenium 钌
  4. Metathesis Catalysts - Ruthenium
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Functional Group 官能团索引
  2. phosphine
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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