3-Hydroxy-N-phenyl-2-naphthamide 3-羟基-N-苯基-2-萘甲酰胺

CAS 92-77-3 MFCD00004096

化学结构图

92-77-3
SMILES: O=C(Nc1ccccc1)c1cc2ccccc2cc1O

化学属性

Mol. FormulaC17H13NO2
Mol. Weight263.29
Density1.422
Melting Point246-248 °C
Appearance 淡黄色晶体。 溶于热硝基苯，微溶于乙醇，不溶于水和纯碱溶液。溶于烧碱溶液呈黄色。
Boiling Point406.53 °C at 760 mmHg

别名和识别编码

Chemical Name3-Hydroxy-N-phenyl-2-naphthamide
CAS Number92-77-3
EC Number202-188-1
Beilstein Registry Number12,505
MDL NumberMFCD00004096
Synonym 3-Hydroxy-N-phenyl-2-naphthamide {LY} 3-Hydroxy-N-phenyl-2-naphthamide {} {LY} 3-Hydroxy-N-phenyl-2-naphthamide {} {} {LY} 3-Hydroxy-N-phenyl-2-naphthamide {} {} {} {LY} 3-Hydroxy-N-phenyl-2-naphthamide {} {} {} {} {LY} 3-Hydroxy-N-phenyl-2-naphthamide {} {} {} {} {} {LY} 3-Hydroxy-N-phenyl-2-naphthamide {} {} {} {} {} {} {LY} 3-Hydroxy-N-phenyl-2-naphthamide {} {} {} {} {} {} {} {LY} 3-Hydroxy-N-phenyl-2-naphthamide {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 3-Hydroxy-N-phenyl-2-naphthamide {} {} {} {} {} {} {} {} {} {LY} 3-Hydroxy-N-phenyl-2-naphthamide {} {} {} {} {} {} {} {} {} {} {LY} 3-Hydroxy-N-phenyl-2-naphthamide {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Hydroxy-N-phenyl-2-naphthamide {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Hydroxy-N-phenyl-2-naphthamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Hydroxy-N-phenyl-2-naphthamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Hydroxy-N-phenyl-2-napht
Reaxys-RN1842678
PubChem Substance ID87570735
Chemical Name Translation3-羟基-N-苯基-2-萘甲酰胺
InChIKeyJFGQHAHJWJBOPD-UHFFFAOYSA-N
LabNetwork Molecule IDLN00225501
Canonical SMILESO=C(C1=C(C=C2C=CC=CC2=C1)O)NC3=CC=CC=C3
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {Chemicalbook} 染料: 冰染染料: 色酚
  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; amide; alcohol; 1fragment

相关文献及参考

  • Beilstein:12,505
  • Short: II/3
  • Short: EINECS

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R51/53
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P333+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes 9
UN Number 3077 UN 3077 9/PG 3
Packing GroupIII
Hazard Class9
RTECSQJ1897400 
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ESKHA5 Eisei Shikenjo Hokoku.  Bulletin of the Institute of Hygienic
   Sciences.  (Kokuritsu Eisei Shikenjo Kagaku, 18-1 Bushitsu Johobu,
   Setagaya-ku, Tokyo 158, Japan)  V.1-    1886-  Volume(issue)/page/year:
   104,51,1986

Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitro

其他信息

  • TCI Shanghai:冰染偶氮组分2 3-Hydroxy-2-naphthanilide,>;97.0%(LC)(T)(92-77-3)
  • MSDS 信息:Naphthol AS(92-77-3).msds
  • MOL 文件:92-77-3.mol
  • Acros Organics:萘酚 AS Naphthol AS, 99%(92-77-3)
  • 方法二:由2,3酸、苯胺在三氯化磷和氯苯存在下，进行缩合，而后蒸馏出氯苯即得。原料消耗(kg/t)2,3酸（100%） 780苯胺（99%） 400三氯化磷（100%） 235氯苯（98%） 220纯碱（98%） 210
  • 色指数:37505
  • Sigma Aldrich:92-77-3(sigmaaldrich)
  • 上游原料:碳酸钠 --> 三氯化磷 --> 氨基苯 --> 氯苯 --> 2-羟基-3-萘甲酸
  • 用途三:广泛用作棉纤维织物染色、印花的打底剂，如与黄色基GC偶合为黄色，与橙色基GC偶合为橙色，与大红色基RC或红色基KB偶合为红色，与大红色基G偶合为国旗红色，与蓝色基VB或蓝色基BB偶合为蓝色，与红色基RC偶合为酱红色，与枣红色基GBC偶合为枣红色。还可用于制造快色素染料和有机颜料。
  • F:10-21
  • 方法一:以 2-羟基-3-萘甲酸 (2，3-酸) 和苯胺为原料，以氯苯 (或甲苯) 为溶剂，在三氯化磷存在下，将 2，3-酸和苯胺缩合，经中和、蒸馏、过滤、干燥得成品。。
  • 图谱信息:萘酚 AS(92-77-3)红外图谱(IR2) 萘酚 AS(92-77-3)质谱(MS) 萘酚 AS(92-77-3)核磁图( 13 CNMR) 萘酚 AS(92-77-3)红外图谱(IR1)
  • 下游产品:颜料红 21 --> 色母粒 --> 坚固大红G --> 金光红 --> 涂料大红 --> 永固红RB
  • 用途二:色酚 AS 主要用于棉染色的打底剂，也用于维纶、黏胶纤维、蚕丝、二醋酸纤维的染色以及棉布印花的打底剂。常与大红色基 G 配合染大红色；与枣红色基 GBC 配合染紫酱色；与橙色基 GC 配合染黄光橙色；与蓝色盐 VB 配合染蓝色等，是最重要的色酚之一。色酚 AS 还用于制造快色素、快胺素、快磺素及有机颜料。
  • 萘酚 AS价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0313 3-羟基-2-萘苯胺 3-Hydroxy-2-naphthanilide 500G 697元 2014/06/02 H0313 3-羟基-2-萘苯胺 3-Hydroxy-2-naphthanilide 25G 151元 2010/06/21 212181000 萘酚 AS Naphthol AS 99% 100 GR 212元
  • 用途一:主要用于生产有机颜料及用于棉纤维，粘胶纤维和部分合成纤维的染色、印花

系列性分类

相关产品推荐