Thiosalicylic Acid 硫代水杨酸

CAS 147-93-3 MFCD00004836

化学结构图

147-93-3
SMILES: O=C(O)c1ccccc1S

化学属性

Mol. FormulaC7H6O2S
Mol. Weight154.19
Density1.49
Melting Point162-165 °C
TSCAYes
Flash Point150 ºC
Solubility溶于热水
Stability对湿度敏感
Appearance 硫代水杨酸(147-93-3)为黄色叶状（冰乙酸）或针状（乙醇水溶液）结晶。熔点165.5℃，158℃ 软化，能升华，易溶于乙酸，微溶于热水，遇空气得到双硫代水杨酸。
Boiling Point247.55 °C at 760 mmHg

别名和识别编码

Chemical NameThiosalicylic acid, 98%
CAS Number147-93-3
Synonym Thiosalicylic acid {LY} Thiosalicylic acid thiosalicylic acid {} {LY} Thiosalicylic acid {} {} {LY} Thiosalicylic acid {} {} {} {LY} Thiosalicylic acid {} {} {} {} {LY} Thiosalicylic acid {} {} {} {} {} {LY} Thiosalicylic acid {} {} {} {} {} {} {LY} Thiosalicylic acid {} {} {} {} {} {} {} {LY} Thiosalicylic acid {} {} {} {} {} {} {} {} {LY} Thiosalicylic acid {} {} {} {} {} {} {} {} {} {LY} Thiosalicylic acid {} {} {} {} {} {} {} {} {} {} {LY} Thiosalicylic acid {} {} {} {} {} {} {} {} {} {} {} {LY} Thiosalicylic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiosalicylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiosalicylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiosalicylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiosalicylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiosalicylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiosa
EC Number205-704-3
Beilstein Registry Number508507
MDL NumberMFCD00004836
PubChem Substance ID5443
Merck Number9360
Reaxys-RN508507
Chemical Name Translation硫代水杨酸
Wiswesser Line NotationSHR BVQ
LabNetwork Molecule IDLN00193129
InChIInChI=1S/C7H6O2S/c8-7(9)5-3-1-2-4-6(5)10/h1-4,10H,(H,8,9)
Canonical SMILESO=C(C1=C(S)C=CC=C1)O
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分类

  • Sulfur & Selenium Compounds
  • Aromatics
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfur Compounds, Thiols/Mercaptans
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; carboxylic acid; thiol; 1fragment

产品应用

  • 测定铁的试剂，液相色谱测定乙基汞硫代水杨酸钠和乙基汞。硫靛染料制备。

相关文献及参考

  • Zarghi, A., et al.: Bioorg., Med., Chem., 17, 5369 (2009),
  • Merck:14,9360
  • Miller, C., et al.: Environ. Sci. Technol., 43, 8548 (2009),
  • Short: EINECS
  • Merck:14,9360 Beilstein:10,125
  • Mecinovic, J., et al.: Anal. Biochem., 393, 215 (2009),
  • Short: III/35C1

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P317
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
RTECSDH3325000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Storage condition 2-8°C {LY} 2-8°C Air & Light Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C
Hazard Codes Xn Xi Xi,Xn 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

其他信息

  • 硫代水杨酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30178984 硫代水杨酸;硫代柳酸;2-巯基苯甲酸;邻巯基苯甲酸 25g 162元 2011/04/16 M0054 硫代水杨酸 Thiosalicylic Acid 25G 211元 2011/04/16 M0054 硫代水杨酸 Thiosalicylic Acid 500G 1750元
  • 下游产品:苯并噻吩 --> 2-(甲基硫代)苯甲酸
  • 用途一:用作有机合成、医药和染料中间体
  • 海关编码:29309070
  • TCI Shanghai:邻巯基苯甲酸 Thiosalicylic Acid,>;90.0%(T)(147-93-3)
  • 用途二:硫柳汞的中间体，也是硫靛蓝色染料中间体，铁测定试剂。
  • Alfa Aesar:硫代水杨酸,98% Thiosalicylic acid, 98%(147-93-3)
  • F:9-23
  • MSDS 信息:2-Mercaptobenzoic acid(147-93-3).msds
  • 用途三:测定铁的试剂，液相色谱测定乙基汞硫代水杨酸钠和乙基汞。硫靛染料制备。
  • 敏感性:Air & Light Sensitive
  • Acros Organics:2-巯基苯甲酸 Thiosalicylic acid, 98%(147-93-3)
  • Sigma Aldrich:147-93-3(sigmaaldrich)
  • 图谱信息:硫代水杨酸(147-93-3)质谱(MS) 硫代水杨酸(147-93-3)红外图谱(IR1) 硫代水杨酸(147-93-3)红外图谱(IR2)
  • 上游原料:氢酸
  • 158℃软化。能升华。露置空气中产生二硫代水杨酸。易溶于醇(200 mg/l)、醚和冰乙酸，溶于热水。半数致死量(小鼠，腹腔)50mg/kg。有刺激性。
  • 方法一:用卤代苯甲酸在铜催化剂存在下与硫氢酸盐反应制得。
  • MOL 文件:147-93-3.mol

系列性分类

  1. Life Science 生命科学
  2. Cancer Research
  3. Carcinogens - Cancer Research
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiols/Mercaptans - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiols/Mercaptans - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiol/Mercaptan Salts

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