Dimethyl fluoromalonate 氟丙二酸二甲酯

CAS 344-14-9 MFCD00054680

化学结构图

344-14-9
SMILES: COC(=O)C(F)C(=O)OC

化学属性

Mol. FormulaC5H7FO4
Mol. Weight150.11
Boiling Point140.3°C at 760 mmHg
Refractive index1.4032
TSCANo
Flash Point111-112°C/45mm
Melting PointN/A

别名和识别编码

Chemical NameDimethyl Fluoromalonate
CAS Number344-14-9
Alfabeta NameDIMETHYLFLUOROMALONATE 2-
MDL NumberMFCD00054680
Synonym Dimethyl 2-fluoromalonate {LY} Dimethyl 2-fluoromalonate {} {LY} Dimethyl 2-fluoromalonate {} {} {LY} Dimethyl 2-fluoromalonate {} {} {} {LY} Dimethyl 2-fluoromalonate {} {} {} {} {LY} Dimethyl 2-fluoromalonate {} {} {} {} {} {LY} Dimethyl 2-fluoromalonate {} {} {} {} {} {} {LY} Dimethyl 2-fluoromalonate {} {} {} {} {} {} {} {LY} Dimethyl 2-fluoromalonate {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} Dimethyl 2-fluoromalonate {} {} {} {} {} {} {} {} {} {LY} Dimethyl 2-fluoromalonate {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl 2-fluoromalonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl 2-fluoromalonate {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl 2-fluoromalonate {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl 2-fluoromalonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl 2-fluoromalonate {} {} {} {} {} {} {} {} {} {}
EC Number000-000-0
Beilstein Registry Number1768414
Chemical Name Translation氟丙二酸二甲酯
LabNetwork Molecule IDLN00009604
PubChem Substance ID2737111
InChIInChI=1S/C5H7FO4/c1-9-4(7)3(6)5(8)10-2/h3H,1-2H3
Canonical SMILESO=C(OC)C(F)C(OC)=O
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分类

  • {uni_hamburg} no charge; ester; 1fragment

相关文献及参考

  • Useful fluorinated building block. Reaction of the Na derivative with ɑ ß-unsaturated ketones or esters has been reported. At room temperature, a normal Michael reaction occurs, but on heating, reaction proceeds by a domino pathway providing a route to fluorinated trisubstituted alkenes: J. Org. Chem., 63, 7525 (1998):
  • Short: III/35C1

安全信息

Warnings IRRITANT-HARMFUL, TOXIC
Packing GroupII
UN Number 3261
Risk Statements
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S2636/37/3945
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Hazard Codes 8 T,C
Signal word Danger
GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P316
  • P301+P330+P331
  • P302+P352
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P361+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard Class8
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒

其他信息

  • 2-氟丙二酸二甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 L16751 氟丙二酸二甲酯, 97% Dimethyl fluoromalonate, 97% 5g 2730元 2010/05/25 L16751 氟丙二酸二甲酯, 97% Dimethyl fluoromalonate, 97% 1g 745元
  • Hazard Note:Toxic
  • MOL 文件:344-14-9.mol
  • Alfa Aesar:氟丙二酸二甲酯,97% Dimethyl fluoromalonate, 97%(344-14-9)
  • MSDS 信息:Dimethyl fluoromalonate(344-14-9).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorous Chemistry 氟化学

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