N-Tert-Butyltrimethylsilylamine N-叔-丁基三甲基甲硅烷基胺

CAS 5577-67-3 MFCD00054891

化学结构图

5577-67-3
SMILES: CC(C)(C)N[Si](C)(C)C

化学属性

Mol. Formula(CH3)3SiNHC(CH3)3
Mol. Weight145.32
Refractive indexn20/D 1.406(lit.)
Boiling Point118-119 °C(lit.)
Density0.762 g/mL at 25 °C(lit.)

别名和识别编码

Chemical NameN-Tert-Butyltrimethylsilylamine
Synonym N-trimethylsilyl-tert-butylamine N-tert-Butyl(trimethylsilyl)amine (tert-Butylamino)trimethylsilane tert-butylamino-trimethyl-silane tert-Butylaminotrimethylsilane {uni_hamburg} Silanamine, N-(1,1-dimethylethyl)-1,1,1-trimethyl- N-(三甲基硅基)-叔丁胺 N-tert-butyltrimethylsilylamine N-tert.-Butyltrimethylsilylamin Silylamine, N-tert-butyl-1,1,1-trimethyl- N-叔丁基三甲基硅基胺 Ethylamine, 1,1-dimethyl-N-(trimethylsilyl)- tert-Butyl-trimethylsilanyl-amine N-(Trimethylsilyl)-tert-butylamine Trimethylsilyl-tert-butylamine
MDL NumberMFCD00054891
CAS Number5577-67-3
PubChem Substance ID138535
Beilstein Registry Number1734528
Chemical Name TranslationN-叔-丁基三甲基甲硅烷基胺
InChIKeyGVHIREZHTRULPT-UHFFFAOYSA-N
InChIInChI=1S/C7H19NSi/c1-7(2,3)8-9(4,5)6/h8H,1-6H3
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Protected Amines
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7 Internet Resource: DOI:10.1007/b55685 RefComment: VII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Hazard Codes C
Risk Statements
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤

系列性分类


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