(S)-(-)-1-(4-bromophenyl)ethylamine (S)-(-)-1-(4-溴苯)乙胺

CAS 27298-97-1 MFCD00066026

化学结构图

27298-97-1
SMILES: C[C@H](N)c1ccc(Br)cc1

化学属性

Mol. FormulaC8H10BrN
Mol. Weight200
Density1.390 g/mL at 20 °C(lit.)
Refractive index1.5660 to 1.5700
Flash Point>110°(230°F)
TSCANo
Boiling Point140-145°/30mm
Melting Point-25
Stability对空气敏感
pH:A

别名和识别编码

Chemical Name(S)-(-)-1-(4-bromophenyl)ethylamine
CAS Number27298-97-1
Alfabeta NameBROMOPHENYLETHYLAMINE S14(())---
MDL NumberMFCD00066026
Synonym (S)-(?)-4-Bromo-α-methylbenzylamine (S)-1-(4-BROMOPHENYL)ETHYLAMINE (S)-(-)-1-AMINO-1-(4-BROMOPHENYL)ETHANE (S)-(-)-p-Bromo-alpha-methylbenzylamine (S)-(-)-4-Bromo--methylbenzylamine (S)-(-)-1-(4-BROMOPHENYL)ETHYLAMINE 99% (S)-(-)-1-(4-Bromophenyl)ethylamine, ChiPros, 99%, ee 98% (S)-(-)-1-(4-溴苯基)乙胺, CHIPROS, 99%, E (S)-(-)-1-(4-BROMOPHENYL)ETHYLAMINE: CHIPROS, 98%, EE 98% Benzenemethanamine, 4-bromo-α-methyl-, (αS)- (s)-(-)-1-(4-bromophenyl)ethylamine, chipros (S)-(-)-1-(4-Bromophenyl)ethylamine, ChiPros, 98%, ee 98+% (S)-(-)-1-(4-溴苯基)乙胺 S(-)-4-BROMO-ALPHA-METHYLBENZYLAMINE 1-(4-溴苯酚)乙基吡啶 (S)-(-)-4-Bromo-α-methylbenzylamine (S)-(-)-4-溴-α-苯乙胺 (S)-(-)-1-(4-BROMOPHENYL)ETHYLAMINE
Beilstein Registry Number5729988
PubChem Substance ID160871282
Chemical Name Translation(S)-(-)-1-(4-溴苯)乙胺
Reaxys-RN5729988
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分类

  • {SNA} Amines, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
  • {SNA} Amines, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Organic Building Blocks
  • {SA} Amines, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Organic Building Blocks

安全信息

Warnings IRRITANT
UN Number 2735
Risk Statements
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Storage condition 对空气敏感，密封避免接触空气 0-10°C Air Sensitive
WGK Germany3
Precautionary statements
  • P303+P361+P353+P310+P363
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P330+P331
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P304+P340
  • P303+P361+P353
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+P340+P310
  • P301+P330+P331+P310
  • P305+P351+P338+P310
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
Signal word
GHS Symbol
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupIII
Hazard Codes C
Hazard Class8

其他信息

  • 敏感性:Air Sensitive
  • (S)-(-)-1-(4-溴苯)乙胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 254932500 (S)-(-)-1-(4-溴苯)乙胺 (S)-(-)-1-(4-Bromophenyl)ethylamine 98% 250 MG 1709元 2010/05/25 L20080 (S)-(-)-1-(4-溴苯基)乙胺, ChiPros, 99%, ee 98% (S)-(-)-1-(4-Bromophenyl)ethylamine, ChiPros, 99%, ee 98% 5g 2450元 2010/05/25 L20080 (S)-(-)-1-(4-溴苯基)乙胺, ChiPros, 99%, ee 98% (S)-(-)-1-(4-Bromophenyl)ethylamine, ChiPros, 99%, ee 98% 25g 9772元
  • 比旋光度:-18 ° (c=2,CH3OH)
  • Sigma Aldrich:27298-97-1(sigmaaldrich)
  • F:10-23
  • MOL 文件:27298-97-1.mol
  • Acros Organics:(S)-(-)-1-(4-Bromophenyl)ethylamine, 98%(27298-97-1)
  • Alfa Aesar:(S)-(-)-1-(4-溴苯基)乙胺,ChiPros,99%,ee98% (S)-(-)-1-(4-Bromophenyl)ethylamine, ChiPros, 99%, ee 98%(27298-97-1)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents

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