• 原料直供
• 试剂商城
• 直接询价

分类

• {uni_hamburg} no charge; amide; 1fragment
• {SNA} Alkyl Fluorinated Building Blocks, Amides, Building Blocks, C2 to C7, Carbonyl Compounds, Chemical Synthesis, Fluorinated Building Blocks, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks

相关文献及参考

• Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
• Short: II/24B Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24B Year: 2000 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-65345-7 ISBN: 978-3-540-65345-5 Internet Resource: DOI:10.1007/b58835 RefComment: VIII, 525 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24B contains an introduction and tables of rotational and centrifugal distortion constants of asymmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
• Short: II/24C Title: Molecular Constants mostly from Microwave,

安全信息

GHS Symbol

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 2 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SKEZAP Shokuhin Eiseigaku Zasshi.  Food Hygiene Journal.  (Nippon Shokuhin
   Eisei Gakkai c/o Shokuhin Eisei Senta, 2-6-1 Jingumae, Shibuya-ku, Tokyo
   150, Japan)  V.1-    1960-  Volume(issue)/page/year: 9,1,1968

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 34 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SKEZAP Shokuhin Eiseigaku Zasshi.  Food Hygiene Journal.  (Nippon Shokuhin
   Eisei Gakkai c/o Shokuhin Eisei Senta, 2-6-1 Jingumae, Shibuya-ku, Tokyo
   150, Japan)  V.1-    1960-  Volume(issue)/page/year: 9,1,1968

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 25 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ABCHA6 Agricultural and Biological Chemistry.  (Maruzen Co. Ltd., POB 5050,
   Tokyo International, Tokyo 100-31, Japan)  V.25-    1961-
   Volume(issue)/page/year: 31,1294,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 4 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag
   New York, Inc., 1971  Volume(issue)/page/year: -,119,1971

TYPE OF TEST            : LD50 - Let

TYPE OF TEST            : Sperm Morphology
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 4 mg/kg
REFERENCE :
   VAAZA2 Virchows Archiv, Abteilung B: Cell Pathology.  (Springer-Verlag,
   Heidelberger Pl. 3, D-1000 Berlin 33, Fed. Rep. Ger.)  V.1-    1968-
   Volume(issue)/page/year: 1,346,1968

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 4 mg/kg
REFERENCE :
   VAAZA2 Virchows Archiv, Abteilung B: Cell Pathology.  (Springer-Verlag,
   Heidelberger Pl. 3, D-1000 Berlin 33, Fed. Rep. Ger.)  V.1-    1968-
   Volume(issue)/page/year: 1,346,1968

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Mammal - species unspecified Lung
DOSE/DURATION           : 300 umol/L
REFERENCE :
   HKXUDL Huanjing Kexue Xuebao.  Environmental Sciences Journal.  (China
   International Book Trading Corp., POB 2820, Beijing, Peop. Rep. China) V.1- 
     1981-  Volume(issue)/page/year: 3,94,1983

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 90 mg/kg
SEX/DURATION            : male 30 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
   EXPEAM Experientia.  (Birkhaeuser Verlag, POB 133, CH-4010 Basel,
   Switzerland)  V.1-    1945-  Volume(issue)/page/year: 20,492,1964

其他信息

• 毒性分级:剧毒
• 下游产品:氟乙酸钠
• 类别:农药
• Hazard Note:Highly Toxic/Irritant
• MOL 文件:640-19-7.mol
• Sigma Aldrich:640-19-7(sigmaaldrich)
• Acros Organics:氟乙酰胺 Fluoroacetamide,98%(640-19-7)
• 可燃性危险特性:遇明火、高热可燃; 遇热或酸分解有毒氟化物和氮氧化物气体
• 急性毒性:口服-大鼠 LD50: 5.75 毫克/公斤; 口服-小鼠 LD50: 25 毫克/公斤
• 用途一:氟乙酰胺用于防治棉花，大豆，高梁，小麦，苹果等蚜虫，柑桔介壳虫及森林螨类等效果很好，尤其对棉花抗性蚜虫特别有效。也用作杀鼠剂。氟乙酰胺对消化道粘膜有一定刺激作用。口服中毒除出现消化道症状外，主要表现为中枢神经系统的过度兴奋，烦燥不安，肌肉震颤，反复发作的全身阵发性和强直性抽搐，部分患者出现精神障碍，该药易损害心肌。我国从1982年6月5日起禁止使用含氟乙酰胺的农药和杀鼠剂，并停止其登记。我国早在1976年就已明令停止生产，1982年，农牧渔业部，卫生部颁发的《农药安全使用规定》中明文规定：不许把氟乙酰胺做为灭鼠药销售和使用。
• 上游原料:四氯乙烯 --> 氯乙酰胺
• 方法一:由氯乙酰胺氟化而得。氟化反应可在二甲苯，四氯乙烯等溶剂中进行；也可采用干法（无溶剂法），即干燥的氯乙酰胺和氟化剂KF加热反应。干法较简便，没有防爆要求，收率也较溶剂法高。将干燥的氟化钾和氯乙酰胺按1.5:1(摩尔比）放入球磨机球磨半小时，把此混料放入预热好的卧式氟化釜，减压下加热反应，得含量为95%的氟乙酰胺，收率72-75%。
• MSDS 信息:2-氟乙酰胺(640-19-7).msds
• 储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
• 外观性质:无臭、无味、不易挥发的白色针状固体。
• 灭火剂:水、砂土、二氧化碳