5-Amino-2-Methylpyridine 2-甲基-5-氨基吡啶

CAS 3430-14-6 MFCD00833389

化学结构图

3430-14-6
SMILES: Cc1ccc(N)cn1

化学属性

Mol. FormulaC6H8N2
Mol. Weight108.14
Melting Point95-99°C
Density1.068
TSCANo
Boiling Point238.4±20.0°C at 760 mmHg

别名和识别编码

Chemical Name5-Amino-2-Methylpyridine
CAS Number3430-14-6
Alfabeta NameAMINOMETHYLPYRIDINE 52---
MDL NumberMFCD00833389
EC Number250-023-7
Beilstein Registry Number22(5)9,208
Synonym 5-Amino-2-picoline {LY} 5-Amino-2-picoline {} {LY} 5-Amino-2-picoline {} {} {LY} 5-Amino-2-picoline {} {} {} {LY} 5-Amino-2-picoline {} {} {} {} {LY} 5-Amino-2-picoline {} {} {} {} {} {LY} 5-Amino-2-picoline {} {} {} {} {} {} {LY} 5-Amino-2-picoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-picoline {} {} {} {} {} {} {} {} {LY} 5-Amino-2-picoline {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-picoline {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-picoline {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-picoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-picoline {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-picoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-picoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-picoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-picoline {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID87559936
Reaxys-RN107053
Chemical Name Translation2-甲基-5-氨基吡啶
InChIInChI=1S/C6H8N2/c1-5-2-3-6(7)4-8-5/h2-4H,7H2,1H3
LabNetwork Molecule IDLN00002529
Canonical SMILESCC1=CC=C(N)C=N1
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分类

  • {SNA} Building Blocks, C6, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines

相关文献及参考

  • Beilstein:22(5)9,208

安全信息

Warnings IRRITANT
Signal word Danger Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P330
  • P302+P352+P312+P361+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Packing GroupIII
UN Number 2811 UN2811
Hazard Codes Xn Xn,Xi
Hazard statements
  • H301+H311
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Class6.1
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 下游产品:5-羟基-2-吡啶羧酸 --> 6-溴-5-甲氧基-2-羧酸吡啶 --> 5-氨基-2-吡啶羧酸 --> 2-氨基-5-羟基吡啶 --> 3-羟基-6-甲基吡啶 --> 萘啶酸 --> 5-甲氧基吡啶-2-羧酸 --> 5-羟基吡啶-2-碳酰肼 --> 5-氯吡啶-2-羧酸 --> 5-羟基吡啶-2-羧酸甲酯 --> 2-甲基-5-甲氧基吡啶 --> 6-甲基-3-甲氧基-2-碘吡啶 --> 3-羟基-2-碘-6-甲基吡啶 --> {[(6-甲基-2-吡啶基)氨基]亚甲基}丙二酸二乙酯
  • Sigma Aldrich:3430-14-6(sigmaaldrich)
  • 上游原料:乙醇 --> 氢氧化钠 --> 盐酸 --> 乙酸乙酯 --> 四氢呋喃 --> 硝酸 --> 溴 --> 氨 --> 钯 --> 1,4-二氧六环 --> 异丙醇 --> 丙二酸二乙酯 --> 磺酰氯 --> 三氟乙酸酐 --> 叔丁醇钾 --> 焦亚硫酸钠 --> 2-甲基吡啶 --> 2-氯-5-硝基吡啶 --> 6-甲基烟酸甲酯
  • 检测方法:HPLC
  • MOL 文件:3430-14-6.mol
  • 存储注意事项:氮气保护
  • 3-氨基-6-甲基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A2053 5-氨基-2-甲基吡啶 5-Amino-2-methylpyridine 5G 1870元 2010/05/25 H27431 5-氨基-2-甲基吡啶, 97% 5-Amino-2-methylpyridine, 97% 250mg 844元 2010/05/25 H27431 5-氨基-2-甲基吡啶, 97% 5-Amino-2-methylpyridine, 97% 1g 2142元
  • Alfa Aesar:5-氨基-2-甲基吡啶,97% 5-Amino-2-methylpyridine, 97%(3430-14-6)
  • TCI Shanghai:5-氨基-2-甲基吡啶 5-Amino-2-picoline,>;98.0%(GC)(T)(3430-14-6)
  • Hazard Note:Harmful

系列性分类

  1. C6 - Pyridines
  1. C6 to C7 - Pyridines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

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